中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE

文献类型:期刊论文

作者WANG W ; LI LM ; XI SQ
刊名acta chimica sinica
出版日期1993
卷号51期号:1页码:59-65
关键词N-ALKANES X-RAY BILAYER C10H21NH3CL BEHAVIOR
ISSN号0567-7351
通讯作者wang w
中文摘要infrared spectroscopy was used to study the structural phase, transitions of laurylammonium chloride in the temperature range from 290 to 365k. it was shown that there is a solid-solid phase transition at 339 k with a pre-transition at 327 k. the infrared spectra indicated that virgin crystals at room temperature form a well-ordered phase with all-trans hydrocarbon chains, and the lengths of n-h...cl hydrogen bonds are different. the spectra suggested that the gauche conformers begin to appear at temperature above 327 k. the spectra at high temperature over 339 k demonstrated that the interaction between the chains decreases, the partial ''melting'' of the chains is obvious, and the hydrogen bonds (n-h...cl) have the same lengths. the main transition and pre-transition are mainly assigned to the intramolecular and intermolecular order-disorder changes, respectively.
收录类别SCI收录期刊论文
语种japanese
公开日期2011-01-19 ; 2011-06-10
源URL[http://ir.ciac.jl.cn/handle/322003/36267]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
WANG W,LI LM,XI SQ. AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE[J]. acta chimica sinica,1993,51(1):59-65.
APA WANG W,LI LM,&XI SQ.(1993).AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE.acta chimica sinica,51(1),59-65.
MLA WANG W,et al."AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE".acta chimica sinica 51.1(1993):59-65.

入库方式: OAI收割

来源:长春应用化学研究所

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