AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE
文献类型：期刊论文
| 作者 | WANG W ; LI LM ; XI SQ |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 1993 |
| 卷号 | 51期号:1页码:59-65 |
| 关键词 | N-ALKANES X-RAY BILAYER C10H21NH3CL BEHAVIOR |
| ISSN号 | 0567-7351 |
| 通讯作者 | wang w |
| 中文摘要 | infrared spectroscopy was used to study the structural phase, transitions of laurylammonium chloride in the temperature range from 290 to 365k. it was shown that there is a solid-solid phase transition at 339 k with a pre-transition at 327 k. the infrared spectra indicated that virgin crystals at room temperature form a well-ordered phase with all-trans hydrocarbon chains, and the lengths of n-h...cl hydrogen bonds are different. the spectra suggested that the gauche conformers begin to appear at temperature above 327 k. the spectra at high temperature over 339 k demonstrated that the interaction between the chains decreases, the partial ''melting'' of the chains is obvious, and the hydrogen bonds (n-h...cl) have the same lengths. the main transition and pre-transition are mainly assigned to the intramolecular and intermolecular order-disorder changes, respectively. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | japanese |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/36267]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | WANG W,LI LM,XI SQ. AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE[J]. acta chimica sinica,1993,51(1):59-65. |
| APA | WANG W,LI LM,&XI SQ.(1993).AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE.acta chimica sinica,51(1),59-65. |
| MLA | WANG W,et al."AN INFRARED SPECTROSCOPIC STUDY ON THE STRUCTURAL PHASE-TRANSITIONS OF LAURYLAMMONIUM CHLORIDE".acta chimica sinica 51.1(1993):59-65. |
入库方式： OAI收割
来源：长春应用化学研究所
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