ELECTROCHEMICAL CATALYSIS AT AN ULTRAMICROELECTRODE MODIFIED WITH REDOX SPECIES
文献类型：期刊论文
| 作者 | CHE GL ; DONG SJ |
| 刊名 | electrochimica acta
 |
| 出版日期 | 1993 |
| 卷号 | 38期号:4页码:581-588 |
| 关键词 | CHEMICALLY MODIFIED ELECTRODES PLASMA-POLYMERIZED VINYLFERROCENE ROTATING-DISK ELECTRODES CROSS-EXCHANGE REACTIONS STEADY-STATE METHOD ION MERCURY SYSTEM COATED ELECTRODES MICROVOLTAMMETRIC ELECTRODES GRAPHITE-ELECTRODES MICRODISK ELECTRODE |
| ISSN号 | 0013-4686 |
| 中文摘要 | general equations of the electrocatalytic reaction at an ultramicroelectrode modified with redox species have been described according to the andrieux saveant model. the electrocatalytic kinetic process has been discussed for the whole set of cases, ie (r), (r + s), (sr) (sr + e), (e), (r + e), (er), (s), (er + s) and (s + e) limiting situations. the effect of gamma on the catalytic steady state current shows that the higher the value of gamma, the lower the catalytic current. the kinetic process shifts rapidly from r to e with increasing values of gamma. it is favorable for catalysis only when gamma is very low. therefore, the redox species modified ultramicroelectrode with thin film is utilized for electrocatalysis, and the larger the radius of ultramicroelectrode, the higher the catalytic efficiency. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/36281]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | CHE GL,DONG SJ. ELECTROCHEMICAL CATALYSIS AT AN ULTRAMICROELECTRODE MODIFIED WITH REDOX SPECIES[J]. electrochimica acta,1993,38(4):581-588. |
| APA | CHE GL,&DONG SJ.(1993).ELECTROCHEMICAL CATALYSIS AT AN ULTRAMICROELECTRODE MODIFIED WITH REDOX SPECIES.electrochimica acta,38(4),581-588. |
| MLA | CHE GL,et al."ELECTROCHEMICAL CATALYSIS AT AN ULTRAMICROELECTRODE MODIFIED WITH REDOX SPECIES".electrochimica acta 38.4(1993):581-588. |
入库方式： OAI收割
来源：长春应用化学研究所
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