HELIX-INDUCED ASYMMETRIC POLYMERIZATION
文献类型:期刊论文
作者 | YU B ; DING MX ; WANG YC ; HU HZ ; WANG FS |
刊名 | makromolekulare chemie-macromolecular symposia
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出版日期 | 1992 |
卷号 | 63页码:279-290 |
关键词 | POLY(TRIPHENYLMETHYL METHACRYLATE) |
ISSN号 | 0258-0322 |
通讯作者 | yu b |
中文摘要 | asymmetric polymerization could be induced by an already formed optically active living prepolymer with one-handed screw sense helix conformation. the usually formed anionic active centre on the prepolymer could be changed to cationic, radical and even of ziegler-natta type. these living prepolymers with various kinds of active centre were all effective to induce a consequent asymmetric polymerization of a monomer which may be other than that in the prepolymer, to afford an optically active helical chain with the same screw sense as that of the prepolymer. eight monomers have been used in the work. optical rotation, circular dichroism and gelpermeation chromatography have been taken to prove the helix-induced asymmetric polymerization. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2011-01-19 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/37095] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | YU B,DING MX,WANG YC,et al. HELIX-INDUCED ASYMMETRIC POLYMERIZATION[J]. makromolekulare chemie-macromolecular symposia,1992,63:279-290. |
APA | YU B,DING MX,WANG YC,HU HZ,&WANG FS.(1992).HELIX-INDUCED ASYMMETRIC POLYMERIZATION.makromolekulare chemie-macromolecular symposia,63,279-290. |
MLA | YU B,et al."HELIX-INDUCED ASYMMETRIC POLYMERIZATION".makromolekulare chemie-macromolecular symposia 63(1992):279-290. |
入库方式: OAI收割
来源:长春应用化学研究所
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