SYNTHESES AND X-RAY STRUCTURES OF BIS(T-BUTYLCYCLOPENTADIENYL)LANTHANIDE CHLORIDE COMPLEXES [(BU(T)CP)2LNCL]2 (LN = PR, GD, ER)
文献类型：期刊论文
| 作者 | SONG SP ; SHEN Q ; JIN SC ; GUAN JW ; LIN YH |
| 刊名 | polyhedron
 |
| 出版日期 | 1992 |
| 卷号 | 11期号:22页码:2857-2861 |
| 关键词 | YTTERBIUM |
| ISSN号 | 0277-5387 |
| 中文摘要 | reaction of lanthanide trichlorides with two equivalents of sodium t-butylcyclopentadienide in thf gave rise to the bis(t-butylcyclopentadienyl)lanthanide chloride complexes [(bu(t)cp)2lncl]2 (ln = pr, gd, er), which were characterized by elemental analysis, ir and h-1 nmr spectroscopy. in addition, the crystal structures of [(butcp)2prcl]2 (1) and [(butcp)2gdcl]2 (2) were determined by single crystal x-ray diffraction at room temperature. the coordination number for pr3+ and gd3+ is 8 and the bond lengths pr-cl and gd-cl are 2.864(2) and 2.771(3) angstrom, respectively. the structural studies showed the complexes to have c2h symmetry. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/37107]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | SONG SP,SHEN Q,JIN SC,et al. SYNTHESES AND X-RAY STRUCTURES OF BIS(T-BUTYLCYCLOPENTADIENYL)LANTHANIDE CHLORIDE COMPLEXES [(BU(T)CP)2LNCL]2 (LN = PR, GD, ER)[J]. polyhedron,1992,11(22):2857-2861. |
| APA | SONG SP,SHEN Q,JIN SC,GUAN JW,&LIN YH.(1992).SYNTHESES AND X-RAY STRUCTURES OF BIS(T-BUTYLCYCLOPENTADIENYL)LANTHANIDE CHLORIDE COMPLEXES [(BU(T)CP)2LNCL]2 (LN = PR, GD, ER).polyhedron,11(22),2857-2861. |
| MLA | SONG SP,et al."SYNTHESES AND X-RAY STRUCTURES OF BIS(T-BUTYLCYCLOPENTADIENYL)LANTHANIDE CHLORIDE COMPLEXES [(BU(T)CP)2LNCL]2 (LN = PR, GD, ER)".polyhedron 11.22(1992):2857-2861. |
入库方式： OAI收割
来源：长春应用化学研究所
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