STUDY ON OPTICAL-ROTATORY OF HELIX POLYMER POLY(TRIPHENYLMETHYL METHACRYLATE)
文献类型:期刊论文
| 作者 | WANG YC ; DING MX ; HU HZ ; WANG FS |
| 刊名 | science in china series b-chemistry
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| 出版日期 | 1992 |
| 卷号 | 35期号:10页码:1161-1166 |
| 关键词 | TRIPHENYLMETHYL METHACRYLATE ASYMMETRIC POLYMERIZATION POLYVINYL COMPOUNDS CHIRALITY STABILITY CATALYSTS |
| ISSN号 | 1001-652x |
| 中文摘要 | the optical rotatory of helix polymer poly(triphenylmethyl methacrylate) (ptrma) has been studied. the specific rotation of ptrma is related with the length of helical chain linearly, while p(n)bar<6 and p(n)bar greater-than-or-equal-to 15. when p(n)bar greater-than-or-equal-to 15, [alpha]d/20 = 1.6 p(n)bar + 290-degrees. the contribution of each repeating unit to [alpha]d/20 is 1.6-degrees. in the 300-600 nm region, the ord of ptrma obeys both the drude equation and moffitt equation. the relationship between the [alpha]d of ptrma and the solvent, concentration and temperature has also been investigated. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/37131] ![]() |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | WANG YC,DING MX,HU HZ,et al. STUDY ON OPTICAL-ROTATORY OF HELIX POLYMER POLY(TRIPHENYLMETHYL METHACRYLATE)[J]. science in china series b-chemistry,1992,35(10):1161-1166. |
| APA | WANG YC,DING MX,HU HZ,&WANG FS.(1992).STUDY ON OPTICAL-ROTATORY OF HELIX POLYMER POLY(TRIPHENYLMETHYL METHACRYLATE).science in china series b-chemistry,35(10),1161-1166. |
| MLA | WANG YC,et al."STUDY ON OPTICAL-ROTATORY OF HELIX POLYMER POLY(TRIPHENYLMETHYL METHACRYLATE)".science in china series b-chemistry 35.10(1992):1161-1166. |
入库方式: OAI收割
来源:长春应用化学研究所
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