SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR ORGANOLANTHANIDE COMPLEXES INVOLVING CYCLOPENTADIENYL AND N-PROPYLOXIDE LIGANDS - X-RAY CRYSTAL-STRUCTURE OF [(C5H5)2YB(MU-OCH2CH2CH3)]2
文献类型：期刊论文
| 作者 | WU ZZ ; XU Z ; YOU XZ ; ZHOU XG ; JIN ZS |
| 刊名 | polyhedron
 |
| 出版日期 | 1992 |
| 卷号 | 11期号:20页码:2673-2678 |
| 关键词 | CRYSTALLOGRAPHIC CHARACTERIZATION CHEMISTRY |
| ISSN号 | 0277-5387 |
| 通讯作者 | wu zz |
| 中文摘要 | by the reaction of cp3ln (cp = c5h5; ln = dy, ho, yb) with equimolar n-propyl alcohol in thf (tetrahydrofuran) at room temperature three new binuclear organolanthanide complexes, [cp2ln(mu-och2ch2ch3)]2 (ln = dy, ho, yb), have been synthesized, as shown by x-ray single-crystal structure analysis for the complex [cp2yb(mu-och2ch2ch3)]2. all the complexes were characterized by elemental analysis, ir and ms spectra. the yb2o2 unit is planar, and the ytterbium atom is coordinated by two cp ring centroids and two oxygen atoms of two n-propyloxide ligands to form a distorted tetrahedral geometry. the average yb-c (cp) bond distance is 2.589(17) angstrom. the average yb-o distance is 2.199(5) angstrom. the yb-yb separation [3.521(1) angstrom] indicates that no metal-metal interaction is present. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/37141]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | WU ZZ,XU Z,YOU XZ,et al. SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR ORGANOLANTHANIDE COMPLEXES INVOLVING CYCLOPENTADIENYL AND N-PROPYLOXIDE LIGANDS - X-RAY CRYSTAL-STRUCTURE OF [(C5H5)2YB(MU-OCH2CH2CH3)]2[J]. polyhedron,1992,11(20):2673-2678. |
| APA | WU ZZ,XU Z,YOU XZ,ZHOU XG,&JIN ZS.(1992).SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR ORGANOLANTHANIDE COMPLEXES INVOLVING CYCLOPENTADIENYL AND N-PROPYLOXIDE LIGANDS - X-RAY CRYSTAL-STRUCTURE OF [(C5H5)2YB(MU-OCH2CH2CH3)]2.polyhedron,11(20),2673-2678. |
| MLA | WU ZZ,et al."SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR ORGANOLANTHANIDE COMPLEXES INVOLVING CYCLOPENTADIENYL AND N-PROPYLOXIDE LIGANDS - X-RAY CRYSTAL-STRUCTURE OF [(C5H5)2YB(MU-OCH2CH2CH3)]2".polyhedron 11.20(1992):2673-2678. |
入库方式： OAI收割
来源：长春应用化学研究所
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