A HIGH-RESOLUTION SOLID-STATE NMR-STUDY OF THE MISCIBILITY, MORPHOLOGY, AND TOUGHENING MECHANISM OF POLYSTYRENE WITH POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) BLENDS
文献类型:期刊论文
作者 | FENG HQ ; FENG ZL ; RUAN HZ ; SHEN LF |
刊名 | macromolecules
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出版日期 | 1992 |
卷号 | 25期号:22页码:5981-5985 |
关键词 | NUCLEAR MAGNETIC-RESONANCE C-13 NMR SPIN-DIFFUSION POLY(2,6-DISUBSTITUTED-1,4-PHENYLENE OXIDES) RELAXATION PARAMETERS POLYETHYLENE POLYMERS FLEXIBILITY POLYBLENDS DEPENDENCE |
ISSN号 | 0024-9297 |
通讯作者 | feng hq |
中文摘要 | an extended goldman-shen pulse sequence was used to observe indirectly the proton spin diffusion in the blends of polystyrene (ps) with poly(2,6-dimethyl-1,4-phenylene oxides) (ppo). the results indicate that the average distance between ps and ppo is less than 5 angstrom in the intimately mixed phase, but there are heterogeneous domains on a 100-angstrom scale. the data of spin relaxation of carbons, t1(c), for homopolymers and their blends suggest that there is a strong pi-pi electron conjugation interaction between the aromatic rings of ps and those of ppo, while the aromatic rings of ppo drive the aromatic rings of ps to move cooperatively. it is the cooperative motion that markedly improves the impact strength of ps. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2011-01-19 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/37143] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | FENG HQ,FENG ZL,RUAN HZ,et al. A HIGH-RESOLUTION SOLID-STATE NMR-STUDY OF THE MISCIBILITY, MORPHOLOGY, AND TOUGHENING MECHANISM OF POLYSTYRENE WITH POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) BLENDS[J]. macromolecules,1992,25(22):5981-5985. |
APA | FENG HQ,FENG ZL,RUAN HZ,&SHEN LF.(1992).A HIGH-RESOLUTION SOLID-STATE NMR-STUDY OF THE MISCIBILITY, MORPHOLOGY, AND TOUGHENING MECHANISM OF POLYSTYRENE WITH POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) BLENDS.macromolecules,25(22),5981-5985. |
MLA | FENG HQ,et al."A HIGH-RESOLUTION SOLID-STATE NMR-STUDY OF THE MISCIBILITY, MORPHOLOGY, AND TOUGHENING MECHANISM OF POLYSTYRENE WITH POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) BLENDS".macromolecules 25.22(1992):5981-5985. |
入库方式: OAI收割
来源:长春应用化学研究所
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