THE SYNTHESIS AND CRYSTAL-STRUCTURE OF MOLYBDENUM-SILICON BLUE
文献类型：期刊论文
| 作者 | WANG EB ; XU L ; SHEN EH ; WANG ZP ; LIN YH ; JIN SC |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 1992 |
| 卷号 | 50期号:9页码:849-857 |
| 关键词 | HETEROPOLY ANIONS |
| ISSN号 | 0567-7351 |
| 通讯作者 | wang eb |
| 中文摘要 | the single crystal of heteropoly blue, hssimo12o40.12h2o, the reduced product of molybdenum-silicon heteropoly acid, was prepared by electrochemical reduction and evaporation in nitrogen atmosphere. the crystal structure of the product was determined. the heteropoly blue h8simo12o40.12h2o, crystallizes space group p1bar a = 1.3769 (3) nm, b = 1.4346 (4) nm, c = 1.4134 (4) nm, alpha = 120.47 (2)-degrees, beta = 110.70 (2)-degrees, gamma = 66.11 (2)-degrees, z = 2, r = 0.0608. the heteropoly blue anion was determined to have keggin structure and alpha-isomer and it remained the structure of the unreduced heteropoly acid anion. but the distortion of the structure and the changes of bond length and bond angle take place obviously. the four mo5+ positions were determined in the structure. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/37151]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | WANG EB,XU L,SHEN EH,et al. THE SYNTHESIS AND CRYSTAL-STRUCTURE OF MOLYBDENUM-SILICON BLUE[J]. acta chimica sinica,1992,50(9):849-857. |
| APA | WANG EB,XU L,SHEN EH,WANG ZP,LIN YH,&JIN SC.(1992).THE SYNTHESIS AND CRYSTAL-STRUCTURE OF MOLYBDENUM-SILICON BLUE.acta chimica sinica,50(9),849-857. |
| MLA | WANG EB,et al."THE SYNTHESIS AND CRYSTAL-STRUCTURE OF MOLYBDENUM-SILICON BLUE".acta chimica sinica 50.9(1992):849-857. |
入库方式： OAI收割
来源：长春应用化学研究所
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