SPECTROELECTROCHEMICAL STUDY OF BILIRUBIN IN DIMETHYL FORMAMIDE
文献类型：期刊论文
| 作者 | DONG SJ ; YANG Y ; CHENG CJ |
| 刊名 | journal of electroanalytical chemistry
 |
| 出版日期 | 1992 |
| 卷号 | 324期号:1-2页码:219-228 |
| 关键词 | VOLTAMMETRY OXIDATION |
| ISSN号 | 0022-0728 |
| 通讯作者 | dong sj |
| 中文摘要 | the electrochemical reduction of bilirubin (br) in dimethyl formamide (dmf) is discussed in detail. the kinetic study of the electroreduction process of br results in values of 7.94 x 10(-6) cm2/s for the diffusion coefficient and about 10(-3) cm/s for the standard heterogeneous electrode reaction rate constant. thin-layer spectroelectrochemical investigations of br exhibit a blue shift and a red shift at e(pc) = -0.6 v and e(pc) = -0.85 v respectively. they also give values of e0' = -1.55 v and n = 1 for the reduction process, and e0' = -1.35 v and n = 1 for the oxidation process. it was found experimentally that as the potential changes from negative to positive, the sequential color changes are similar to those of some of the color components in visible light. a mechanism for br electroreduction in dmf has been proposed. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/37261]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | DONG SJ,YANG Y,CHENG CJ. SPECTROELECTROCHEMICAL STUDY OF BILIRUBIN IN DIMETHYL FORMAMIDE[J]. journal of electroanalytical chemistry,1992,324(1-2):219-228. |
| APA | DONG SJ,YANG Y,&CHENG CJ.(1992).SPECTROELECTROCHEMICAL STUDY OF BILIRUBIN IN DIMETHYL FORMAMIDE.journal of electroanalytical chemistry,324(1-2),219-228. |
| MLA | DONG SJ,et al."SPECTROELECTROCHEMICAL STUDY OF BILIRUBIN IN DIMETHYL FORMAMIDE".journal of electroanalytical chemistry 324.1-2(1992):219-228. |
入库方式： OAI收割
来源：长春应用化学研究所
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