C-13 AND H-1 NMR STUDIES OF SOLUTION STRUCTURE OF LANTHANIDE COMPLEX WITH GLYCYL-GLYCINE
文献类型:期刊论文
作者 | Ren JM ; Niu CJ ; Pei FK ; Wang WY ; Ni JA |
刊名 | acta physico-chimica sinica
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出版日期 | 1992 |
卷号 | 8期号:2页码:270-273 |
关键词 | GLYCYL-GLYCINE LANTHANIDE COMPLEX SOLUTION STRUCTURE NUCLEAR MAGNETIC RESONANCE |
ISSN号 | 1000-6818 |
通讯作者 | ren jm |
中文摘要 | c-13 and h-1 nmr technique was used to study the interaction of gly-gly with heavy lanthanide cations dy3+, ho3+, er3+, tm3+ and yb3+ in aqueous solution. the stability constants for the 1:1 and 1:2 complexes of gly-gly with ho3+ and yb3+ were determined from the titration curves of chemical shift versus concentration ratio of lanthanide to gly-gly. the solution structure of the ln-gly-gly complex was analyzed based upon the c-13 and h-1 lanthanide induced shifts and the results show that in the complex gly gly is coordinated to the lanthanide ion through the carboxyl oxygens with the backbone of the ligand in an extended state. |
收录类别 | SCI收录期刊论文 |
语种 | 中文 |
WOS记录号 | WOS:000207574200026 |
公开日期 | 2011-01-19 |
源URL | [http://ir.ciac.jl.cn/handle/322003/37395] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Ren JM,Niu CJ,Pei FK,et al. C-13 AND H-1 NMR STUDIES OF SOLUTION STRUCTURE OF LANTHANIDE COMPLEX WITH GLYCYL-GLYCINE[J]. acta physico-chimica sinica,1992,8(2):270-273. |
APA | Ren JM,Niu CJ,Pei FK,Wang WY,&Ni JA.(1992).C-13 AND H-1 NMR STUDIES OF SOLUTION STRUCTURE OF LANTHANIDE COMPLEX WITH GLYCYL-GLYCINE.acta physico-chimica sinica,8(2),270-273. |
MLA | Ren JM,et al."C-13 AND H-1 NMR STUDIES OF SOLUTION STRUCTURE OF LANTHANIDE COMPLEX WITH GLYCYL-GLYCINE".acta physico-chimica sinica 8.2(1992):270-273. |
入库方式: OAI收割
来源:长春应用化学研究所
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