CYCLIC VOLTAMMETRIC AND SPECTROELECTROCHEMICAL STUDIES OF COPPER IN ALKALINE-SOLUTION
文献类型：期刊论文
| 作者 | DONG SJ ; XIE YW ; CHENG GJ |
| 刊名 | electrochimica acta
 |
| 出版日期 | 1992 |
| 卷号 | 37期号:1页码:17-22 |
| 关键词 | CUPRIC HYDROXIDE FILMS ANODIC-OXIDATION ELECTRODES BEHAVIOR SURFACES LAYERS METAL CU2O XPS |
| ISSN号 | 0013-4686 |
| 通讯作者 | dong sj |
| 中文摘要 | the behaviour of the electroplated copper film electrode on tin oxide/glass or glassy carbon surface was studied in potassium hydroxide medium by cyclic voltammetry and in situ transmission spectroelectrochemistry. the results indicate that the electroplated copper film electrode is similar to a copper electrode and cyclic voltammetry with this electrode affords more resolution. the anodic peaks were found to correspond successively to the adsorption of oxygen, the formation of a surface layer of cu2o, the formation of a surface layer of cu(oh)2 or cuo and formation of a thick multilayer film of cuo. this is the first time it has been proposed that a surface layer of cu(oh)2 or cuo is formed from the oxidation of the surface layer of cu2o. similarly, a clear interpretation is presented that the cathodic peaks correspond successively to the reduction of cuo to cu2o, the reductions of cu2o to cu and the soluble cu(ii) species to cu. on the other hand, a shoulder peak related to the chemical transformation of cu(oh)2 to cuo was first observed. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/37403]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | DONG SJ,XIE YW,CHENG GJ. CYCLIC VOLTAMMETRIC AND SPECTROELECTROCHEMICAL STUDIES OF COPPER IN ALKALINE-SOLUTION[J]. electrochimica acta,1992,37(1):17-22. |
| APA | DONG SJ,XIE YW,&CHENG GJ.(1992).CYCLIC VOLTAMMETRIC AND SPECTROELECTROCHEMICAL STUDIES OF COPPER IN ALKALINE-SOLUTION.electrochimica acta,37(1),17-22. |
| MLA | DONG SJ,et al."CYCLIC VOLTAMMETRIC AND SPECTROELECTROCHEMICAL STUDIES OF COPPER IN ALKALINE-SOLUTION".electrochimica acta 37.1(1992):17-22. |
入库方式： OAI收割
来源：长春应用化学研究所
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