Trace Element Analysis by PIYE and ICP-AES of Raw Material and Ancient Serpentine Artifacts from China
文献类型：期刊论文
| 作者 | Dong JQ(董俊卿); Wang YY(王永亚); Gan FX(干福熹); Li QH(李青会) |
| 刊名 | 光谱学与光谱分析
 |
| 出版日期 | 2016 |
| 卷号 | 36期号:11页码:3780 |
| 通讯作者 | djqing_2005@126.com ; qinghuil@sina.com |
| 中文摘要 | 以蛇纹石这一中国传统的玉材为对象,旨在通过微量元素含量分析来探索古代蛇纹石玉器原料的可能来源。采用无损的外束质子激发X射线荧光技术(PIXE)对来自中国几个典型矿区的蛇纹石样品主量元素和微量元素进行了分析。同时也采用有损的电感耦合等离子体原子发射光谱技术(ICP-AES)对这些蛇纹石样品的微量元素含量进行了比较分析。结果表明,两种分析方法所获取的蛇纹石微量元素含量趋势具有一致性,说明PIXE无损分析技术可以应用于蛇纹石的微量元素分析研究。讨论了蛇纹石的微量元素含量与地质成因之间的关系,这些蛇纹石的微量元素 |
| 英文摘要 | This work mainly talks about serpentine mineral with the aim to explore the possible raw materials sources of ancient serpentine artifacts by trace element content analysis. The major and trace elements of serpentine samples from several typical deposits in China were nondestructively determined by external-beam proton -induced X-ray emission (PIXE). For comparison, trace element concentrations were destructively measured by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The results showed the trend of the trace element contents of serpentine jade obtained by the two methods have preferably coherence, which indicate that the nondestructive technique of PIXE can be applied to trace element analysis of serpentine. The relationship between trace element contents and serpentine formation mechanism was discussed. The difference of the trace elements contents in these serpentine minerals is obvious. It can be used to distinguish the different kinds of serpentine formed by different mechanisms. A low amount of Ni and almost no Cr and Co were found in type I serpentine group mineral, whereas significant amounts of Cr, Co and Ni were found in Type II serpentine group mineral. The chemical composition of 18 ancient serpentine artifacts were analyzed by PIXE, they were unearthed from 14 sites and tombs in provinces of Zhejing, Jiangsu, Henan, Anhui and Hubei and dated from Neolithic Age to the Warring States Period (4585 BC-231 BC). By comparing the trace element contents between ancient serpentine artifacts and two kinds of serpentine samples, the provenance of ancient serpentine artifacts were preliminarily inferred. It is beneficial to try to explore the possible raw material of ancient serpentine artifacts based on the relationship between the trace element contents and serpentine formation mechanism in this article. |
| 收录类别 | SCI |
| 资助信息 | 973 Program [2012CB720906]; Shanghai R&D Public Service Platform Construction Project [13DZ2295800]; National Key Technology Support Program [2013BAK08B08] |
| WOS记录号 | WOS:000388251100058 |
| 源URL | [http://ir.siom.ac.cn/handle/181231/28262]  |
| 专题 | 上海光学精密机械研究所_高密度光存储技术实验室 |
| 作者单位 | 中国科学院上海光学精密机械研究所 |
| 推荐引用方式 GB/T 7714 | Dong JQ,Wang YY,Gan FX,et al. Trace Element Analysis by PIYE and ICP-AES of Raw Material and Ancient Serpentine Artifacts from China[J]. 光谱学与光谱分析,2016,36(11):3780. |
| APA | 董俊卿,王永亚,干福熹,&李青会.(2016).Trace Element Analysis by PIYE and ICP-AES of Raw Material and Ancient Serpentine Artifacts from China.光谱学与光谱分析,36(11),3780. |
| MLA | 董俊卿,et al."Trace Element Analysis by PIYE and ICP-AES of Raw Material and Ancient Serpentine Artifacts from China".光谱学与光谱分析 36.11(2016):3780. |
入库方式： OAI收割
来源：上海光学精密机械研究所
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