Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet
文献类型：期刊论文
| 作者 | Zhang, Chi; Wu, Chao; Humphrey, Mark G.; Li, Longhua; Song, Junling; Yang, Gang |
| 刊名 | Inorg. Chem.
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:3页码:1340 |
| 通讯作者 | chizhang@tongji.edu.cn |
| 英文摘要 | Two novel noncentrosymmetric metal borates, Ba-2[B4O7(OH)(2)] (1) and Na[B5O7(OH)(2)](H2O) (2), have been obtained by hydrothermal and surfactant-thermal means. Compound 1 consists of novel one-dimensional borate chains formed by B3O9 and B3O8 rings, assembled into a three-dimensional (3D) framework by Ba2+ cations. The structure of 2 exhibits double-helical chains constructed from B5O10 primary building units, which are interconnected via Na+ cations and H-bonding interactions to generate a 3D framework. Second-harmonic-generation (SHG) measurements show that 1 shows a phase-matching powder SHG response of similar to 2.2 x KH2PO4 (KDP), while 2 exhibits a weak SHG response. The cutoff edges of 1 and 2 are similar to 242 and similar to 221 nm, respectively, which suggests that they are potential ultraviolet nonlinear optical (NLO) materials. Band structures and NLO properties have also been theoretically studied. |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [51432006, 50925207, 51172100]; Ministry of Science and Technology of China [2011DFG52970]; Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]; Ministry of Education; State Administration of Foreign Experts Affairs [B13025]; 100 Talents Program of CAS; Australian Research Council |
| WOS记录号 | WOS:000393630300039 |
| 源URL | [http://ir.siom.ac.cn/handle/181231/28078]  |
| 专题 | 上海光学精密机械研究所_中科院强激光材料重点实验室 |
| 作者单位 | 中国科学院上海光学精密机械研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, Chi,Wu, Chao,Humphrey, Mark G.,et al. Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet[J]. Inorg. Chem.,2017,56(3):1340. |
| APA | Zhang, Chi,Wu, Chao,Humphrey, Mark G.,Li, Longhua,Song, Junling,&Yang, Gang.(2017).Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet.Inorg. Chem.,56(3),1340. |
| MLA | Zhang, Chi,et al."Facile Syntheses of Ba-2[B4O7(OH)(2)] and Na[B5O7(OH)(2)](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet".Inorg. Chem. 56.3(2017):1340. |
入库方式： OAI收割
来源：上海光学精密机械研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。