中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction

文献类型:期刊论文

作者Wang, Guoxiong1; Ye, Yifan1,2; Cai, Fan1,2; Yan, Chengcheng1,2; Li, Yanshuo3; Bao, Xinhe1
刊名JOURNAL OF ENERGY CHEMISTRY
出版日期2017-11-01
卷号26期号:6页码:1174-1180
关键词Zeolitic imidazolate frameworks Two-step pyrolysis Oxygen reduction reaction Zinc-air battery Polymer electrolyte membrane fuel cell
英文摘要Zeolitic imidazolate frameworks (ZIFs) are widely employed in catalyst synthesis as parental materials for electrochemical energy storage and conversion. Herein, we have demonstrated a facile synthesis of highly efficient catalyst for oxygen reduction reaction in both alkaline and acidic medium, which is derived from ZIF-8 functionalized with ammonium ferric citrate via two-step pyrolysis in Ar and NH3 atmosphere. The results reveal that the catalytic activity improvement after NH3 pyrolysis benefits from mesopore-dominated morphology and high utilization of Fe-containing active sites. The optimum catalyst shows excellent performance in zinc-air battery and polymer electrolyte membrane fuel cell tests. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
研究领域[WOS]Chemistry ; Energy & Fuels ; Engineering
关键词[WOS]METAL-ORGANIC FRAMEWORKS ; AIR BATTERIES ; FUEL-CELLS ; IRON NANOPARTICLES ; FE/N/C-CATALYSTS ; IONIC LIQUIDS ; MASS ACTIVITY ; ACTIVE-SITES ; ACIDIC MEDIA ; CARBON
收录类别SCI
语种英语
WOS记录号WOS:000415600300014
源URL[http://cas-ir.dicp.ac.cn/handle/321008/149680]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
推荐引用方式
GB/T 7714
Wang, Guoxiong,Ye, Yifan,Cai, Fan,et al. Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(6):1174-1180.
APA Wang, Guoxiong,Ye, Yifan,Cai, Fan,Yan, Chengcheng,Li, Yanshuo,&Bao, Xinhe.(2017).Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction.JOURNAL OF ENERGY CHEMISTRY,26(6),1174-1180.
MLA Wang, Guoxiong,et al."Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction".JOURNAL OF ENERGY CHEMISTRY 26.6(2017):1174-1180.

入库方式: OAI收割

来源:大连化学物理研究所

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