Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones
文献类型：期刊论文
| 作者 | Zheng, Guangfan1; Xia, Jintao1,2; Kong, Lingheng1,2; Zhou, Xukai1,2; Li, Xingwei1 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2017-11-03 |
| 卷号 | 19期号:21页码:5972-5975 |
| 英文摘要 | An efficient synthesis of disubstituted acrylic acids has been realized via Rh(III)-catalyzed C-H activation of (hetero)arenes and coupling with four-membered methyleneoxetanones under redox-neutral conditions. In most cases, the reactions are silver-free, and the products are exclusively E-selective with a broad substrate scope. The transformation proceeds via ortho C-H activation followed by selective olefin insertion and beta-oxygen elimination. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | PALLADIUM-CATALYZED HYDROCARBOXYLATION ; CARBON-DIOXIDE ; FORMIC-ACID ; REGIOSELECTIVE HYDROCARBOXYLATION ; RHODIUM CATALYSIS ; CARBOXYLIC-ACIDS ; ALLYLIC ALCOHOLS ; BOND ACTIVATION ; ARENES ; ALKYNES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000414723900066 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149683]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Guangfan,Xia, Jintao,Kong, Lingheng,et al. Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones[J]. ORGANIC LETTERS,2017,19(21):5972-5975. |
| APA | Zheng, Guangfan,Xia, Jintao,Kong, Lingheng,Zhou, Xukai,&Li, Xingwei.(2017).Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones.ORGANIC LETTERS,19(21),5972-5975. |
| MLA | Zheng, Guangfan,et al."Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones".ORGANIC LETTERS 19.21(2017):5972-5975. |
入库方式： OAI收割
来源：大连化学物理研究所
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