Photocatalytic coupling of amines to imidazoles using a Mo-ZnIn2S4 catalyst
文献类型：期刊论文
| 作者 | Wang, Min2; Li, Lihua2; Lu, Jianmin2; Luo, Nengchao1,2; Zhang, Xiaochen2; Wang, Feng2 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2017-11-07 |
| 卷号 | 19期号:21页码:5172-5177 |
| 英文摘要 | Substituted imidazoles are traditionally synthesized by co-condensation of multiple feedstocks. Herein, we report a new route for the synthesis of substituted imidazoles via photocyclization of readily available amines at room temperature. The reaction is achieved by the visible-light-induced C-C/C-N bond coupling and subsequent dehydrogenation reaction over Mo-ZnIn2S4 as a heterogeneous photocatalyst. A wide range of amines were converted into the corresponding tri-and tetra-substituted imidazoles with up to 96% total yields. The simplicity, high efficiency and mild condition merits of this new reaction will enable it to be useful in synthetic transformations. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ONE-POT SYNTHESIS ; C-H ARYLATION ; VISIBLE-LIGHT PHOTOCATALYSIS ; PHOTOREDOX CATALYSIS ; ROOM-TEMPERATURE ; BOND FORMATION ; 1,2,4,5-TETRASUBSTITUTED IMIDAZOLES ; ALPHA-MNO2 CATALYST ; ALKYL-HALIDES ; METAL-FREE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000414147100018 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149698]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Min,Li, Lihua,Lu, Jianmin,et al. Photocatalytic coupling of amines to imidazoles using a Mo-ZnIn2S4 catalyst[J]. GREEN CHEMISTRY,2017,19(21):5172-5177. |
| APA | Wang, Min,Li, Lihua,Lu, Jianmin,Luo, Nengchao,Zhang, Xiaochen,&Wang, Feng.(2017).Photocatalytic coupling of amines to imidazoles using a Mo-ZnIn2S4 catalyst.GREEN CHEMISTRY,19(21),5172-5177. |
| MLA | Wang, Min,et al."Photocatalytic coupling of amines to imidazoles using a Mo-ZnIn2S4 catalyst".GREEN CHEMISTRY 19.21(2017):5172-5177. |
入库方式： OAI收割
来源：大连化学物理研究所
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