In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O
文献类型:期刊论文
作者 | Luo, Yang1,2; Xu, Jie1; Zhang, Shujing1,2; Sun, Yuxia1,2; Wang, Xinhong3; Gao, Jin1; Ma, Hong1; Wang, Tianlong1,3 |
刊名 | CHEMISTRY-AN ASIAN JOURNAL
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出版日期 | 2017-11-02 |
卷号 | 12期号:21页码:2790-2793 |
关键词 | dual-metal fabrication organic-inorganic hybrids photocatalysis zeolitic imidazolate frameworks |
英文摘要 | We successfully fabricate a well-defined inorganic/organic hybrid Cu2O@Cu/Co-ZIF (ZIF = zeolitic imidazolate frameworks) by use of growth of dual-metal Cu/Co-ZIF on the obtained Cu2O hollow spheres. The key point of the strategy is coupling the in situ self-sacrificing template. Cu2O and the coordination of metal ions (Cu+ and Co2+) with 2-methylimidazole. This new hybrid was characterized by powder X-ray diffraction, (scanning) transmission electron microscopy, energy-dispersive spectroscopy mapping, in situ FT-IR spectroscopy, UV/Vis diffuse reflection spectroscopy, N-2 sorption measurements, and electron spin resonance. It was evidenced that Cu/Co-ZIF nanocrystals have been assembled to continuous shells surrounding the Cu2O cores as well as in the voids between layers and inner pores. Cu2O@Cu/Co-ZIF exhibits visible light responsiveness and holds potential as narrow band gap semiconductor and visible photocatalyst. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | METAL-ORGANIC FRAMEWORK ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; CORE-SHELL ; THERMAL-CONVERSION ; NANOPOROUS CARBONS ; HIGH-PERFORMANCE ; FACILE SYNTHESIS ; NANOPARTICLES ; SELECTIVITY ; CATALYSIS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000414338400003 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149708] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Dalian Polytech Univ, Sch Text & Mat Engn, Dalian 116034, Peoples R China |
推荐引用方式 GB/T 7714 | Luo, Yang,Xu, Jie,Zhang, Shujing,et al. In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(21):2790-2793. |
APA | Luo, Yang.,Xu, Jie.,Zhang, Shujing.,Sun, Yuxia.,Wang, Xinhong.,...&Wang, Tianlong.(2017).In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O.CHEMISTRY-AN ASIAN JOURNAL,12(21),2790-2793. |
MLA | Luo, Yang,et al."In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O".CHEMISTRY-AN ASIAN JOURNAL 12.21(2017):2790-2793. |
入库方式: OAI收割
来源:大连化学物理研究所
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