中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
NHTs Effect on the Enantioselectivity of Ru(II) Complex Catalysts Bearing a Chiral Bis(NHTs)-Substituted Imidazolyl-Oxazolinyl-Pyridine Ligand for Asymmetric Transfer Hydrogenation of Ketones

文献类型:期刊论文

作者Chai, Huining2,3; Yu, Zhengkun1,2; Liu, Tingting2,3
刊名ORGANOMETALLICS
出版日期2017-11-13
卷号36期号:21页码:4136-4144
英文摘要Pincer-type ruthenium(II)-NNN complex catalysts bearing a chiral bis(NHTs)-substituted imidazolyl-oxazolinyl-pyridine ligand were synthesized and structurally characterized by NMR, IR, elemental analysis, and X-ray single-crystal crystallographic determinations. The two NHTs groups substituted on the imidazolyl moiety of the chiral NNN ligand exhibited a remarkable effect on the enantioselectivity of the Ru(II)-NNN complexes for the asymmetric transfer hydrogenation (ATH) of ketones. The Ru(II)-NNN complex bearing a chiral (NHTs),substituted imidazolyl-(isopropyl)oxazolinyl-pyridine ligand exhibited excellent catalytic activity, reaching an enantioselectivity up to 99.9% ee for the target alcohol products.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]NOYORI-IKARIYA CATALYST ; RUTHENIUM(II) COMPLEXES ; CARBONYL-COMPOUNDS ; H-2 HYDROGENATION ; PINCER COMPLEXES ; AROMATIC KETONES ; NNN LIGAND ; ALCOHOLS ; IMINES ; WATER
收录类别SCI
语种英语
WOS记录号WOS:000415392000009
源URL[http://cas-ir.dicp.ac.cn/handle/321008/149747]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Chai, Huining,Yu, Zhengkun,Liu, Tingting. NHTs Effect on the Enantioselectivity of Ru(II) Complex Catalysts Bearing a Chiral Bis(NHTs)-Substituted Imidazolyl-Oxazolinyl-Pyridine Ligand for Asymmetric Transfer Hydrogenation of Ketones[J]. ORGANOMETALLICS,2017,36(21):4136-4144.
APA Chai, Huining,Yu, Zhengkun,&Liu, Tingting.(2017).NHTs Effect on the Enantioselectivity of Ru(II) Complex Catalysts Bearing a Chiral Bis(NHTs)-Substituted Imidazolyl-Oxazolinyl-Pyridine Ligand for Asymmetric Transfer Hydrogenation of Ketones.ORGANOMETALLICS,36(21),4136-4144.
MLA Chai, Huining,et al."NHTs Effect on the Enantioselectivity of Ru(II) Complex Catalysts Bearing a Chiral Bis(NHTs)-Substituted Imidazolyl-Oxazolinyl-Pyridine Ligand for Asymmetric Transfer Hydrogenation of Ketones".ORGANOMETALLICS 36.21(2017):4136-4144.

入库方式: OAI收割

来源:大连化学物理研究所

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