Enhanced sulfur dioxide electrooxidation performance on a modified XC-72 carbon catalyst
文献类型：期刊论文
| 作者 | Zheng, Limin1; Zhao, Qing1,2; Hou, Ming1; Jiang, Shangfeng1,2; Ai, Jun1; Shao, Zhigang1 |
| 刊名 | JOURNAL OF SOLID STATE ELECTROCHEMISTRY
 |
| 出版日期 | 2017-11-01 |
| 卷号 | 21期号:11页码:3113-3120 |
| 关键词 | Modified XC-72 Pyridinic N SO2 electrooxidation Pyrolysis Optimized pore structure |
| 英文摘要 | Vulcan XC-72 is a carbon catalyst that is widely used in electrochemistry. The electrooxidation of SO2 plays a significant role in the domain of environmental protection. In this work, successive thermal and pyrolytic processes were applied to Vulcan XC-72 in order to obtain a modified catalyst that promotes SO2 electrooxidation to a much greater degree than Vulcan XC-72 does. The preparation of this modified XC-72 involved three steps: doping, pore creation, and carbonization. These modification processes were shown to greatly increase the catalytic activity of the modified XC-72 during SO2 electrooxidation. The catalytic performance of the modified XC-72 towards SO2 electrooxidation was characterized via linear sweep voltammograms and cyclic voltammograms; the results showed that the onset potential and the E (imax/2) obtained with the modified XC-72 were 60 mV and 128 mV lower, respectively, than attained with Vulcan XC-72. The structural and physical properties of the modified XC-72 were characterized using TEM, XPS, and BET. The increased surface area and optimized pore structure of the modified XC-72, as well as the presence of pyridinic N constituents in this material, are believed to contribute to its enhanced capacity to catalyze the electrooxidation of SO2. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Electrochemistry |
| 研究领域[WOS] | Electrochemistry |
| 关键词[WOS] | MEMBRANE FUEL-CELLS ; ACIDIC MEDIA ; ELECTROCHEMICAL-BEHAVIOR ; SO2 ADSORPTION ; AQUEOUS SO2 ; HYDROGEN-PRODUCTION ; ACTIVATED CARBONS ; GOLD ELECTRODES ; OXIDATION ; ELECTROCATALYSTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000413763100005 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149769]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Limin,Zhao, Qing,Hou, Ming,et al. Enhanced sulfur dioxide electrooxidation performance on a modified XC-72 carbon catalyst[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY,2017,21(11):3113-3120. |
| APA | Zheng, Limin,Zhao, Qing,Hou, Ming,Jiang, Shangfeng,Ai, Jun,&Shao, Zhigang.(2017).Enhanced sulfur dioxide electrooxidation performance on a modified XC-72 carbon catalyst.JOURNAL OF SOLID STATE ELECTROCHEMISTRY,21(11),3113-3120. |
| MLA | Zheng, Limin,et al."Enhanced sulfur dioxide electrooxidation performance on a modified XC-72 carbon catalyst".JOURNAL OF SOLID STATE ELECTROCHEMISTRY 21.11(2017):3113-3120. |
入库方式： OAI收割
来源：大连化学物理研究所
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