Direct catalytic hydrogenation of CO2 to formate over a Schiff-base-mediated gold nanocatalyst
文献类型：期刊论文
| 作者 | Liu, Qinggang2,3; Yang, Xiaofeng3; Li, Lin3; Miao, Shu3; Li, Yong1,4; Li, Yanqin2; Wang, Xinkui2; Huang, Yanqiang3; Zhang, Tao3 |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2017-11-10 |
| 卷号 | 8 |
| 英文摘要 | Catalytic transformation of CO2 to formate is generally realized through bicarbonate hydrogenation in an alkaline environment, while it suffers from a thermodynamic sink due to the considerable thermodynamic stability of the bicarbonate intermediate. Here, we devise a route for the direct catalytic conversion of CO2 over a Schiff-base-modified gold nanocatalyst that is comparable to the fastest known nanocatalysts, with a turnover number (TON) of up to 14,470 over 12 h at 90 degrees C. Theoretical calculations and spectral analysis results demonstrate that the activation of CO2 can be achieved through a weakly bonded carbamate zwitterion intermediate derived from a simple Lewis base adduct of CO2. However, this can only occur with a hydrogen lacking Lewis base center in a polar solvent. This finding offers a promising avenue for the direct activation of CO2 and is likely to have considerable implications in the fields of CO2 conversion and gold catalytic chemistry. |
| WOS标题词 | Science & Technology |
| 类目[WOS] | Multidisciplinary Sciences |
| 研究领域[WOS] | Science & Technology - Other Topics |
| 关键词[WOS] | CARBON-DIOXIDE ; FORMIC-ACID ; CARBAMATE FORMATION ; ROOM-TEMPERATURE ; KINETICS ; IDENTIFICATION ; CONVERSION ; MOLECULES ; MECHANISM ; METHANOL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000414869200006 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149779]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Bremen, Ctr Environm Res & Sustainable Technol, D-28359 Bremen, Germany 2.Dalian Univ Technol, Sch Chem, State Key Lab Fine Chem, Dalian 116024, Peoples R China 3.Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Univ Bremen, Inst Appl & Phys Chem, D-28359 Bremen, Germany |
| 推荐引用方式 GB/T 7714 | Liu, Qinggang,Yang, Xiaofeng,Li, Lin,et al. Direct catalytic hydrogenation of CO2 to formate over a Schiff-base-mediated gold nanocatalyst[J]. NATURE COMMUNICATIONS,2017,8. |
| APA | Liu, Qinggang.,Yang, Xiaofeng.,Li, Lin.,Miao, Shu.,Li, Yong.,...&Zhang, Tao.(2017).Direct catalytic hydrogenation of CO2 to formate over a Schiff-base-mediated gold nanocatalyst.NATURE COMMUNICATIONS,8. |
| MLA | Liu, Qinggang,et al."Direct catalytic hydrogenation of CO2 to formate over a Schiff-base-mediated gold nanocatalyst".NATURE COMMUNICATIONS 8(2017). |
入库方式： OAI收割
来源：大连化学物理研究所
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