Synergism from interfaces between Cu and crystalline ZrO2 nanosheets fabricated by acetic complex method for oxalates hydrogenation
文献类型：期刊论文
| 作者 | Liu, Yanting1,5; Ding, Jian4; Zhang, Juan1; Dong, Mei1; Wang, Yaxiong4; He, Wenxiu4; Han, Xiaoxing4; Liu, Kefeng2; Jiang, Zheng3; Chen, Jiangang1 |
| 刊名 | MOLECULAR CATALYSIS
 |
| 出版日期 | 2017-09-01 |
| 卷号 | 438页码:93-102 |
| 关键词 | Oxalate hydrogenation Cu/ZrO2 catalyst Acetic complex method Dielectric constant Synergistic effect |
| 英文摘要 | Herein, the Cu species uniformly combining with highly crystalline ZrO2 nanosheets had been prepared by a one-pot acetic complex method. The selectivity to ethylene glycol of 98.9%, which corresponds to 99.8% conversion of diethyl oxalate was obtained over the one prepared by using acetic acid (AC) both as the complex agent and solvent. In addition, a stable performance was achieved (life span of >160 h). It also showed good performance in hydrogenation of dimethyl oxalate (95.7 h(-1) turnover frequency). Essentially, solvents with different dielectric constant employed in complexation process had a prominent influence on the structure and catalytic activity of Cu/ZrO2 catalyst via solvation. Besides, complexation process was also important since AC could be regarded as L-type ligands in a low dielectric constant solvent, forming of ion-clusters which resulted in exclusive formation of the Cu-O-Zr interface after calcination. Evidently, the surface synergistic effect held the key to the continuous hydrogenation reaction related to the activation of the carbonyl groups and the hydrogen dissociation, thus creating a synergetic nanoenvironment for the successful completion of the "multi step turning into one-step" in the series reaction. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | DIMETHYL OXALATE ; ETHYLENE-GLYCOL ; DIETHYL OXALATE ; CATALYTIC PERFORMANCE ; TIO2 NANOPARTICLES ; CU/SIO2 CATALYSTS ; CU/ZRO2 CATALYSTS ; ETHANOL SYNTHESIS ; CARBOXYLIC-ACID ; OXIDE CATALYSTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000406565200011 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149802]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Shanxi Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 2.PetroChina Co Ltd, Petrochem Res Inst, Beijing 100029, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 4.Inner Mongolia Univ Sci & Technol, Sch Chem & Chem Engn, Baotou 014010, Inner Mongolia, Peoples R China 5.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yanting,Ding, Jian,Zhang, Juan,et al. Synergism from interfaces between Cu and crystalline ZrO2 nanosheets fabricated by acetic complex method for oxalates hydrogenation[J]. MOLECULAR CATALYSIS,2017,438:93-102. |
| APA | Liu, Yanting.,Ding, Jian.,Zhang, Juan.,Dong, Mei.,Wang, Yaxiong.,...&Chen, Jiangang.(2017).Synergism from interfaces between Cu and crystalline ZrO2 nanosheets fabricated by acetic complex method for oxalates hydrogenation.MOLECULAR CATALYSIS,438,93-102. |
| MLA | Liu, Yanting,et al."Synergism from interfaces between Cu and crystalline ZrO2 nanosheets fabricated by acetic complex method for oxalates hydrogenation".MOLECULAR CATALYSIS 438(2017):93-102. |
入库方式： OAI收割
来源：大连化学物理研究所
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