A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition
文献类型：期刊论文
| 作者 | Yi, Baolian1; Hong, Shaojing1,2; Hou, Ming1; Zhang, Hongjie1,2; Jiang, Yongyi1,2; Shao, Zhigang1 |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2017-08-10 |
| 卷号 | 245页码:395-401 |
| 关键词 | proton exchange membrane fuel cell electrospun electrode underpotential deposition |
| 英文摘要 | A novel PEMFC electrode (E-U electrode) with ultralow platinum is prepared by electrospinning and underpotential deposition techniques. The platinum skin (Ptskin) is in situ deposited on the surface of Pd nanoparticle in the electrospun Pd/ C catalyst layer. The energy-dispersive X-ray spectroscopy (EDS) mapping of the cross-section of a single fiber confirms that the distribution of Pd/C@ Pt-skin catalysts and Nafion1 ionomer matches well in the E-U electrode. The high porosity and large electrochemical surface area (ECSA) of the E-U electrode mitigates the oxygen transfer resistance. The peak power density of the E-U electrode arrives at 0.62 W cm(-2) with a Pt loading of 19 mg cm(-2), which is higher than that of the conventional electrode (0.55 W cm(-2)) with a Pt loading of 100 mg cm(-2). The degradation rate of peak power density of the E-U electrode is only 4.8% after accelerated stability test (AST) for 30000 cyclic voltammetry (CV) cycles, demonstrating a better durability than that of the conventional electrode. The enhanced durability of the E-U electrode is attributed to nanofiber structure and interaction between Pd and Pt in the Pd/C@ Pt-skin catalyst. (C) 2017 Published by Elsevier Ltd. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Electrochemistry |
| 研究领域[WOS] | Electrochemistry |
| 关键词[WOS] | OXYGEN REDUCTION REACTION ; SUPPORTED PD NANOPARTICLES ; CORE-SHELL ; MONOLAYER ELECTROCATALYSTS ; O-2 REDUCTION ; CATALYSTS ; CATHODE ; LAYER ; NANOSTRUCTURES ; RESISTANCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000406762700043 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149818]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Fuel Cell Syst & Engn Lab, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yi, Baolian,Hong, Shaojing,Hou, Ming,et al. A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition[J]. ELECTROCHIMICA ACTA,2017,245:395-401. |
| APA | Yi, Baolian,Hong, Shaojing,Hou, Ming,Zhang, Hongjie,Jiang, Yongyi,&Shao, Zhigang.(2017).A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition.ELECTROCHIMICA ACTA,245,395-401. |
| MLA | Yi, Baolian,et al."A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition".ELECTROCHIMICA ACTA 245(2017):395-401. |
入库方式： OAI收割
来源：大连化学物理研究所
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