Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones
文献类型：期刊论文
| 作者 | Liu, Tingting1,3; Chai, Huining1,3; Wang, Liandi1; Yu, Zhengkun1,2 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2017-08-14 |
| 卷号 | 36期号:15页码:2914-2921 |
| 英文摘要 | Dinuclear ruthenium(II)-NNN complexes were efficiently assembled by means of coordinatively unsaturated 16-electron mononuclear ruthenium(II)-pyrazolyl-imidazolyl-pyridine complex and 4,4'-linked bipyridine ligands. The diruthenium(II)-NNN complex assembled through 4,4'-(CH2)(3)-bipyridine exhibited exceptionally high catalytic activity for the transfer hydrogenation (TH) of ketones in refluxing 2-propanol and reached TOF values up to 1.4 x 10(7) h(-1), demonstrating a remarkable cooperative effect from the ruthenium(II)-NNN functionalities. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ASYMMETRIC TRANSFER HYDROGENATION ; PYRAZOLYL-IMIDAZOLYL LIGAND ; HETEROMETALLIC COMPLEXES ; METAL-COMPLEXES ; NNN LIGAND ; BEARING ; OXIDATION ; OXYGEN ; WATER ; COOPERATIVITY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000407869100025 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149821]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Tingting,Chai, Huining,Wang, Liandi,et al. Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones[J]. ORGANOMETALLICS,2017,36(15):2914-2921. |
| APA | Liu, Tingting,Chai, Huining,Wang, Liandi,&Yu, Zhengkun.(2017).Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones.ORGANOMETALLICS,36(15),2914-2921. |
| MLA | Liu, Tingting,et al."Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones".ORGANOMETALLICS 36.15(2017):2914-2921. |
入库方式： OAI收割
来源：大连化学物理研究所
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