Selection of Oxygen Permeation Models for Different Mixed Ionic-Electronic Conducting Membranes
文献类型：期刊论文
| 作者 | Yang, Weishen2; Zhu, Xuefeng2; Liu, Yan1,2; Li, Wenping1,2; Zhu, Yue1,2 |
| 刊名 | AICHE JOURNAL
 |
| 出版日期 | 2017-09-01 |
| 卷号 | 63期号:9页码:4043-4053 |
| 关键词 | oxygen permeation models MIEC membranes oxygen vacancy oxygen partial pressure perovskite |
| 英文摘要 | Permeation data of several mixed ionic-electronic conducting (MIEC) membranes were analyzed by two oxygen permeation models (i.e., Zhu's model and Xu-Thomson's model), respectively, to find a concise method to guide the choice of permeation models. We found that Zhu's model can well fit the permeation data of perovskite-type membranes, like Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) and BaCe0.05Fe0.95O3-delta (BCF), and dual-phase membranes, like 75 wt % Ce0.85Sm0.15O1.925-25 wt % Sm0.6Sr0.4Al0.3Fe0.7O3-delta (SDC-SSAF), whose oxygen vacancy concentrations are almost independent of the oxygen partial pressure at elevated temperatures. However, Zhu's model was not appropriate for membranes whose oxygen vacancy concentration changed obviously with oxygen partial pressure at elevated temperatures, such as La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) and La0.7Sr0.3CoO3-delta (LSC). On the contrary, XuThomson's model can fit the data of LSCF and LSC well, but it is inapplicable for BSCF, BCF, and SDC-SSAF. Therefore, the dependence of oxygen vacancy concentration on oxygen partial pressure was suggested as an index for the selection of the permeation models. (C) 2017 American Institute of Chemical Engineers |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | HOLLOW-FIBER MEMBRANE ; OXIDE FUEL-CELLS ; PEROVSKITE-TYPE OXIDES ; DUAL-PHASE MEMBRANES ; PARTIAL OXIDATION ; AIR SEPARATION ; STRUCTURAL STABILITY ; COMPOSITE MEMBRANE ; CERAMIC MEMBRANES ; EXCHANGE KINETICS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000407192500034 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149947]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Weishen,Zhu, Xuefeng,Liu, Yan,et al. Selection of Oxygen Permeation Models for Different Mixed Ionic-Electronic Conducting Membranes[J]. AICHE JOURNAL,2017,63(9):4043-4053. |
| APA | Yang, Weishen,Zhu, Xuefeng,Liu, Yan,Li, Wenping,&Zhu, Yue.(2017).Selection of Oxygen Permeation Models for Different Mixed Ionic-Electronic Conducting Membranes.AICHE JOURNAL,63(9),4043-4053. |
| MLA | Yang, Weishen,et al."Selection of Oxygen Permeation Models for Different Mixed Ionic-Electronic Conducting Membranes".AICHE JOURNAL 63.9(2017):4043-4053. |
入库方式： OAI收割
来源：大连化学物理研究所
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