Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization
文献类型：期刊论文
| 作者 | Zhang, Wen-Xiong2; Zhang, Yongliang2; Chi, Yue2; Wei, Junnian2; Yang, Qi2; Yang, Zhenqiang1; Chen, Hui1; Yang, Ruina1; Xi, Zhenfeng1,2 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2017-08-14 |
| 卷号 | 36期号:15页码:2982-2986 |
| 英文摘要 | Aromatic 1,1,2,2-tetralithiodigalloles 5 with a Ga-Ga bond were realized. Reaction of 1,4-dilithio-1,3-butadienes 6 with 0.5 equiv of GaCl3 afforded lithium spirogallane ate complexes 7 in excellent isolated yields. Reduction of the above ate complexes 7 with an excess amount of lithium generated the 1,1,2,2-tetralithiodigalloles 5 in moderate isolated yields. The structures of compounds 5 and 7 were both determined by single-crystal X-ray structural analysis. The 1,1,2,2-tetralithiodigalloles 5 contained two aromatic dilithiogalloles connected by a Ga-Ga bond. The aromaticity of 5 was confirmed by both experimental measurements (X-ray structural analysis, NMR spectroscopy) and theoretical analysis (ISE, NICS). |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | IN-IN BONDS ; MOLECULAR-STRUCTURE ; GALLIUM-GALLIUM ; AL-AL ; ORGANOELEMENT COMPOUNDS ; STANNOLE DIANION ; TRANSITION-METAL ; CHEMISTRY ; METALLABENZENES ; COMPLEXES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000407869100034 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149948]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Henan Acad Sci, Henan Inst Chem Co Ltd, Zhengzhou 450002, Henan, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Wen-Xiong,Zhang, Yongliang,Chi, Yue,et al. Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization[J]. ORGANOMETALLICS,2017,36(15):2982-2986. |
| APA | Zhang, Wen-Xiong.,Zhang, Yongliang.,Chi, Yue.,Wei, Junnian.,Yang, Qi.,...&Xi, Zhenfeng.(2017).Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization.ORGANOMETALLICS,36(15),2982-2986. |
| MLA | Zhang, Wen-Xiong,et al."Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization".ORGANOMETALLICS 36.15(2017):2982-2986. |
入库方式： OAI收割
来源：大连化学物理研究所
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