One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone
文献类型：期刊论文
| 作者 | Zhang, Tao2; Song, Lei1,2; Zheng, Mingyuan2; Pang, Jifeng2; Sebastian, Joby2; Wang, Wentao2; Qu, Minjie1; Zhao, Jian1; Wang, Xinhong1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2017-08-07 |
| 卷号 | 19期号:15页码:3515-3519 |
| 英文摘要 | An efficient and green method for the synthesis of 2-hydroxymethyl-5-methylpyrazine was achieved from biomass derived 1,3-dihydroxyacetone and diammonium phosphate via a one-pot reaction. The product yield was as high as 72% under optimized conditions of pH = 8.0-9.1 at 90 degrees C for 1 hour in a dioxane and water mixture as a solvent. A possible reaction mechanism was proposed according to the reaction kinetics, NMR and in situ ATR-IR characterization studies. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | REDUCTIVE AMINATION ; PRIMARY AMINES ; ETHYLENE-GLYCOL ; CATALYSTS ; ACID ; 2-METHYLPYRAZINE ; CONVERSION ; OXIDATION ; PYRAZINE ; AMMONIA |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000406615800005 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149951]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Polytech Univ, Mat Sci & Engn, Dalian 116034, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Tao,Song, Lei,Zheng, Mingyuan,et al. One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone[J]. GREEN CHEMISTRY,2017,19(15):3515-3519. |
| APA | Zhang, Tao.,Song, Lei.,Zheng, Mingyuan.,Pang, Jifeng.,Sebastian, Joby.,...&Wang, Xinhong.(2017).One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone.GREEN CHEMISTRY,19(15),3515-3519. |
| MLA | Zhang, Tao,et al."One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone".GREEN CHEMISTRY 19.15(2017):3515-3519. |
入库方式： OAI收割
来源：大连化学物理研究所
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