Effect of Catalyst Preparation on Hydroisomerization of n-Heptane over Pt/Silicalite-1
文献类型：期刊论文
| 作者 | Liu, Guodong1,2; Shi, Lihua1,2; Song, Xiangen3; Guo, Hongchen1,2 |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2017-10-01 |
| 卷号 | 147期号:10页码:2549-2557 |
| 关键词 | Platinum Silicalite-1 Bi-functional catalyst Isomerization n-Heptane |
| 英文摘要 | The isomerization of n-heptane was comparatively investigated over Pt catalysts prepared by deposition (Pt/S-1-DP) and impregnation precipitation (Pt/S-1-IMP) method with a low loading, separately. It was found that Pt/S-1-DP catalyst produced a much higher catalytic conversion compared with the counterpart catalyst prepared by impregnation. Combined with various characterization techniques, the better performance over Pt/S-1-DP was attributed to not only the well improved dispersity and the smaller size of Pt particles but also the faster transfer of reactive species between Pt sites and acid sites. The activity could be improved by increasing the reduction temperature. Moreover, the (de)hydrogenation of Pt over Pt/S-1 catalyst was verified by in situ infrared spectroscopy through H/D isotope exchange experiment. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CHAIN NORMAL-PARAFFINS ; SELECTIVE ISOMERIZATION ; BECKMANN REARRANGEMENT ; ZEOLITE NANOSHEETS ; MOLECULAR-SIEVES ; BETA ZEOLITES ; SITES ; METAL ; SILICALITE-1 ; PERFORMANCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000411875100010 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150101]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Dalian Univ Technol, Dept Chem & Engn Catalysis, Dalian 116024, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Guodong,Shi, Lihua,Song, Xiangen,et al. Effect of Catalyst Preparation on Hydroisomerization of n-Heptane over Pt/Silicalite-1[J]. CATALYSIS LETTERS,2017,147(10):2549-2557. |
| APA | Liu, Guodong,Shi, Lihua,Song, Xiangen,&Guo, Hongchen.(2017).Effect of Catalyst Preparation on Hydroisomerization of n-Heptane over Pt/Silicalite-1.CATALYSIS LETTERS,147(10),2549-2557. |
| MLA | Liu, Guodong,et al."Effect of Catalyst Preparation on Hydroisomerization of n-Heptane over Pt/Silicalite-1".CATALYSIS LETTERS 147.10(2017):2549-2557. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。