Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters
文献类型：期刊论文
| 作者 | Guo, Lisheng1,2; Sun, Jian1; Wei, Jian1,2; Wen, Zhiyong1,2; Xu, Hengyong1; Ge, Qingjie1 |
| 刊名 | JOURNAL OF ENERGY CHEMISTRY
 |
| 出版日期 | 2017-07-01 |
| 卷号 | 26期号:4页码:632-638 |
| 关键词 | Fischer-Tropsch synthesis Promoters Synergistic effect Iron-based catalysts Hydrocarbons |
| 英文摘要 | A sustainable strategy for Fischer-Tropsch iron catalysts is successfully achieved by embedding of synergistic promoters from a renewable resource, corncob. The iron-based catalysts, named as "corncob-driven" catalysts, are composed of iron species supported on carbon as primary active components and various minerals (K, Mg, Ca, and Si, etc.) as promoters. The corncob-driven catalysts are facilely synthesized by a one-pot hydrothermal treatment under mild conditions. The characterization results indicate that the formation of iron carbides from humboldtine is clearly enhanced and the morphology of catalyst particles tends to be more regular microspheres after adding corncob. It is observed that the optimized corncob-driven catalyst exhibits a higher conversion than without promoters' catalyst in Fischer-Tropsch synthesis (ca. 73% vs. ca. 49%). More importantly, a synergistic effect exists in multiple promoters from corncob that can enhance heavy hydrocarbons selectivity and lower CO2 selectivity, obviously different from the catalyst with promoters from chemicals. The proposed synthesis route of corncob-driven catalysts provides new strategies for the utilization of renewable resources and elimination of environmental pollutants from chemical promoters. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering |
| 关键词[WOS] | MANGANESE CATALYST ; NANOPARTICLES ; SELECTIVITY ; POTASSIUM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000412776100006 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150107]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Lisheng,Sun, Jian,Wei, Jian,et al. Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(4):632-638. |
| APA | Guo, Lisheng,Sun, Jian,Wei, Jian,Wen, Zhiyong,Xu, Hengyong,&Ge, Qingjie.(2017).Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters.JOURNAL OF ENERGY CHEMISTRY,26(4),632-638. |
| MLA | Guo, Lisheng,et al."Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters".JOURNAL OF ENERGY CHEMISTRY 26.4(2017):632-638. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。