Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols
文献类型：期刊论文
| 作者 | Wang, Qingfu1,3; Chai, Huining1,3; Yu, Zhengkun2,3 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2017-09-25 |
| 卷号 | 36期号:18页码:3638-3644 |
| 英文摘要 | Dimeric pincer-type ruthenium(II)-NNN complexes bearing an unsymmetrical pyrazolyl-pyridylamino-pyridine ligand were prepared and characterized by NMR, elemental analysis, and X-ray single crystal structural determination. These complexes exhibited very high catalytic activity for both transfer hydrogenation of ketones and acceptorless dehydrogenation of secondary alcohols, achieving TOF values up to 1.9 x 10(6) h(-1) in the transfer hydrogenation of ketones. The high catalytic activity of the Ru(II) complex catalysts is attributed to the presence of the unprotected NH functionality in the ligand and hemilabile unsymmetrical coordination environment around the central metal atoms in the complex. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ASYMMETRIC TRANSFER HYDROGENATION ; CHIRAL IRIDIUM CATALYSTS ; IRON PINCER COMPLEX ; SELECTIVE HYDROGENATION ; IMIDAZOLYL LIGAND ; N-HETEROCYCLES ; CARBONYL-COMPOUNDS ; AMINO-ALCOHOLS ; NNN LIGAND ; ESTERS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000411914000024 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150208]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Qingfu,Chai, Huining,Yu, Zhengkun. Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols[J]. ORGANOMETALLICS,2017,36(18):3638-3644. |
| APA | Wang, Qingfu,Chai, Huining,&Yu, Zhengkun.(2017).Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols.ORGANOMETALLICS,36(18),3638-3644. |
| MLA | Wang, Qingfu,et al."Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols".ORGANOMETALLICS 36.18(2017):3638-3644. |
入库方式： OAI收割
来源：大连化学物理研究所
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