Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization
文献类型：期刊论文
| 作者 | Xi, Zhenfeng1,2; Zhang, Yongliang2; Wei, Junnian2; Chi, Yue2; Zhang, Xuan2; Zhang, Wen-Xiong2 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2017-04-12 |
| 卷号 | 139期号:14页码:5039-5042 |
| 英文摘要 | Since the concept of aromaticity represents one of the most fundamental principles in chemistry, the search for unprecedented and exciting aromatic systems, therefore, continues to drive research in this area. Herein we report the synthesis and characterization of Spiro metalla-aromatics, in which the transition metal (Pd, Pt, or Rh) is the Spiro atom, that cross-conjugates two aromatic five-membered metallacycles. These Spiro metalla-aromatics tend to take square planar geometries, with the dihedral angle being influenced by the steric repulsion between the alpha-positioned substituents. Rationalized and classified via both experimental measurements (X-ray structural analysis, NMR spectroscopy, XPS, etc.) and theoretical analysis (DFT calculation, ISE, AICD, NICS, and CMOs), all these fundamental observations extend the concept of aromaticity and organometallic chemistry. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TRANSITION-METAL ; CHEMISTRY ; METALLABENZYNES ; DELOCALIZATION ; COMPLEXES ; MOLECULES ; LIGANDS ; STABILIZATION ; ACTIVATION ; DIANIONS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000399353800015 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150340]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xi, Zhenfeng,Zhang, Yongliang,Wei, Junnian,et al. Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(14):5039-5042. |
| APA | Xi, Zhenfeng,Zhang, Yongliang,Wei, Junnian,Chi, Yue,Zhang, Xuan,&Zhang, Wen-Xiong.(2017).Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(14),5039-5042. |
| MLA | Xi, Zhenfeng,et al."Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.14(2017):5039-5042. |
入库方式： OAI收割
来源：大连化学物理研究所
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