Activity and Stability of (Pr1-xNdx)(2)NiO4 as Cathodes for Solid Oxide Fuel Cells
文献类型：期刊论文
| 作者 | Cheng, Mojie3; Dogdibegovic, Emir1; Guan, Wanbing1,2; Yan, Jingbo1,3; Zhou, Xiao-Dong1 |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 2016 |
| 卷号 | 163期号:13页码:F1344-F1349 |
| 英文摘要 | Single phase (Pr1-xNdx)(2)NiO4 cathode powders (x = 0, 0.25, 0.50, 0.75, and 1.0) were synthesized via a glycine-nitrate combustion and high temperature calcination. Anode supported cells were used to investigate the cathode property. A reproducible performance, within 9% for each cathode composition, was observed providing a wealth of data for quantitative studies. Area specific resistance analysis and i-V measurements between 650 and 850 degrees C showed a decrease in the cell performance with increasing Nd content. Impedance spectrum analysis suggests that the decline in performance results from an increase in electrode polarization. While Pr2NiO4 cells showed significant performance degradation of 6.40%/1,000 hours, the degradation rate for (Pr0.75Nd0.25)(2)NiO4 cells was reduced by an order of magnitude (0.56%/1,000 hours) with a 7% lower power output. Likewise, the cathodes with a higher Nd content showed further improvement in performance stability with a marginal degradation rate of 0.06%/1,000 hours. (C) The Author(s) 2016. Published by ECS. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Electrochemistry ; Materials Science, Coatings & Films |
| 关键词[WOS] | ELECTROCHEMICAL PERFORMANCE ; CURRENT COLLECTORS ; IMPEDANCE SPECTRA ; ANODE ; PR2NIO4 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000389155900094 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150431]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ South Carolina, Dept Chem Engn, Columbia, SC 29208 USA 2.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cells, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Mojie,Dogdibegovic, Emir,Guan, Wanbing,et al. Activity and Stability of (Pr1-xNdx)(2)NiO4 as Cathodes for Solid Oxide Fuel Cells[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2016,163(13):F1344-F1349. |
| APA | Cheng, Mojie,Dogdibegovic, Emir,Guan, Wanbing,Yan, Jingbo,&Zhou, Xiao-Dong.(2016).Activity and Stability of (Pr1-xNdx)(2)NiO4 as Cathodes for Solid Oxide Fuel Cells.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,163(13),F1344-F1349. |
| MLA | Cheng, Mojie,et al."Activity and Stability of (Pr1-xNdx)(2)NiO4 as Cathodes for Solid Oxide Fuel Cells".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 163.13(2016):F1344-F1349. |
入库方式： OAI收割
来源：大连化学物理研究所
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