Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers
文献类型：期刊论文
| 作者 | Wang, Hongwei1; Ye, Mingliang1; Liu, Zhongshan1,2; Ou, Junjie1; You, Xin1,2 |
| 刊名 | ACS Applied Materials & Interfaces
 |
| 出版日期 | 2016-11-23 |
| 卷号 | 8期号:46页码:32060-32067 |
| 关键词 | hydrazide amide porous organic polymer hollow structure enrichment of glycopeptide |
| 英文摘要 | Four kinds of either hydrazide-linked or amide-linked polymers were facilely synthesized by using hydrazine, tetrakis(4-aminophenyl)methane (TAPM), terephthaloyl chloride (TPC), and trimesoyl chloride (TMC) as building blocks. The morphology, porosity, composition, and surface property of polymers were characterized by scanning electron microscopy, transmission electron microscopy, nitrogen adsorption-desorption-measurement, C-13/CP-MAS NMR, X-ray photoelectron spectroscopy, etc. The results indicated that building blocks had important effects on morphology and porosity. Poly(TMC-TAPM) synthesized with TMC and TAPM showed the highest surface area of 241.9 m(2) g(-1). In addition, note that a hollow structure with similar to 20 run wall thickness was formed in poly(TMC hydrazine) prepared with TMC and hydrazine. Further study indicated that both carboxyl groups (-COOH) and hydrazide groups (-CONH-NH2) existed on the surface of poly(TMC-hydrazine), besides the mainly hydrazide linkage (-CONH-NHOC-). Taking advantages of good hydrophilicity and special functional groups on the surface, we finally adopted poly(TMC hydrazine) to enrich glycopeptides from tryptic digest via both hydrophilic interaction chromatography method with identification of 369 unique N-glycosylation sites and hydrazide chemistry method with identification of 88 unique N-glycosylation sites, respectively. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 关键词[WOS] | SOLID-PHASE EXTRACTION ; INTERACTION LIQUID-CHROMATOGRAPHY ; INTRINSIC MICROPOROSITY PIMS ; MAGNETIC NANOPARTICLES ; STATIONARY-PHASE ; HYDROGEN STORAGE ; ROOM-TEMPERATURE ; CO2 CAPTURE ; FRAMEWORKS ; GLYCOPEPTIDES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000388913900068 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150437]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Hongwei,Ye, Mingliang,Liu, Zhongshan,et al. Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers[J]. ACS Applied Materials & Interfaces,2016,8(46):32060-32067. |
| APA | Wang, Hongwei,Ye, Mingliang,Liu, Zhongshan,Ou, Junjie,&You, Xin.(2016).Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers.ACS Applied Materials & Interfaces,8(46),32060-32067. |
| MLA | Wang, Hongwei,et al."Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers".ACS Applied Materials & Interfaces 8.46(2016):32060-32067. |
入库方式： OAI收割
来源：大连化学物理研究所
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