A review of dynamical resonances in A plus BC chemical reactions
文献类型：期刊论文
| 作者 | Sun, Zhigang1,5,6; Zhang, Donghui1,5,6; Yang, Xueming1,5,6; Ren, Zefeng1,2,3,4 |
| 刊名 | REPORTS ON PROGRESS IN PHYSICS
 |
| 出版日期 | 2017-02-01 |
| 卷号 | 80期号:2 |
| 关键词 | transition state reactive resonance Feshbach resonance shape resonance potential energy surface crossed beam scattering quantum wave-packet method |
| 英文摘要 | The concept of the transition state has played an important role in the field of chemical kinetics and reaction dynamics. Reactive resonances in the transition-state region can dramatically enhance the reaction probability; thus investigation of the reactive resonances has attracted great attention from chemical physicists for many decades. In this review, we mainly focus on the recent progress made in probing the elusive resonance phenomenon in the simple A + BC reaction and understanding its nature, especially in the benchmark F/Cl + H-2 and their isotopic variants. The signatures of reactive resonances in the integral cross section, differential cross section (DCS), forward-and backward-scattered DCS, and anion photodetachment spectroscopy are comprehensively presented in individual prototype reactions. The dynamical origins of reactive resonances are also discussed in this review, based on information on the wave function in the transition-state region obtained by time-dependent quantum wave-packet calculations. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Physics, Multidisciplinary |
| 研究领域[WOS] | Physics |
| 关键词[WOS] | DIFFERENTIAL CROSS-SECTIONS ; POTENTIAL-ENERGY SURFACE ; WAVE-PACKET METHOD ; TRANSITION-STATE SPECTROSCOPY ; HYDROGEN-EXCHANGE REACTION ; SCATTERING RESONANCES ; BIMOLECULAR REACTIONS ; F+H-2 REACTION ; F PLUS ; MOLECULAR-BEAM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000391575400001 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151847]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Peking Univ, ICQM, Beijing 100871, Peoples R China 3.Peking Univ, Sch Phys, Beijing 100871, Peoples R China 4.Collaborat Innovat Ctr Quantum Matter, Beijing 100871, Peoples R China 5.Univ Sci & Technol China, Ctr Adv Chem Phys, 96 Jinzhai Rd, Hefei 230026, Peoples R China 6.Univ Sci & Technol China, Frontier Ctr Quantum Sci & Technol 2011, 96 Jinzhai Rd, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Zhigang,Zhang, Donghui,Yang, Xueming,et al. A review of dynamical resonances in A plus BC chemical reactions[J]. REPORTS ON PROGRESS IN PHYSICS,2017,80(2). |
| APA | Sun, Zhigang,Zhang, Donghui,Yang, Xueming,&Ren, Zefeng.(2017).A review of dynamical resonances in A plus BC chemical reactions.REPORTS ON PROGRESS IN PHYSICS,80(2). |
| MLA | Sun, Zhigang,et al."A review of dynamical resonances in A plus BC chemical reactions".REPORTS ON PROGRESS IN PHYSICS 80.2(2017). |
入库方式： OAI收割
来源：大连化学物理研究所
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