Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review
文献类型：期刊论文
| 作者 | Lin, Jian1; Li, Lin1; Li, Xiaoyu1,2; Wang, Aiqin1; Wang, Xiaodong1; Zhang, Tao1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016-12-01 |
| 卷号 | 37期号:12页码:2039-2052 |
| 关键词 | Catalysis Microcalorimetry Reactivity Energetics Binding strength Catalyst characterization |
| 英文摘要 | The formations and transformations of the chemical bonds of reactants and intermediates on catalyst surfaces occur in conjunction with the evolution of heat during catalytic reactions. Measurement of this evolved heat is helpful in terms of understanding the nature of the interactions between the catalyst and the adsorbed species, and provides insights into the reactivity of the catalyst. Although various techniques have previously been applied to assessments of evolved heat, direct measurements using a Tian-Calvet microcalorimeter are currently the most reliable method for this purpose. In this review, we summarize the relationship between the adsorption/reaction energetics determined by microcalorimetry and the reactivrties of supported catalysts, and examine the important role of microcalorimetry in understanding catalytic performance from the energetic point of view. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | ACID-BASE PROPERTIES ; POLYCRYSTALLINE GOLD CATALYSTS ; TEMPERATURE CO OXIDATION ; N-BUTANE ISOMERIZATION ; GAS-PHASE DEHYDRATION ; SULFATED ZIRCONIA ; NICKEL-CATALYSTS ; ISOBUTANE DEHYDROGENATION ; HETEROGENEOUS CATALYSIS ; TUNGSTATED ZIRCONIA |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000391777500001 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151860]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Jian,Li, Lin,Li, Xiaoyu,et al. Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(12):2039-2052. |
| APA | Lin, Jian,Li, Lin,Li, Xiaoyu,Wang, Aiqin,Wang, Xiaodong,&Zhang, Tao.(2016).Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review.CHINESE JOURNAL OF CATALYSIS,37(12),2039-2052. |
| MLA | Lin, Jian,et al."Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review".CHINESE JOURNAL OF CATALYSIS 37.12(2016):2039-2052. |
入库方式： OAI收割
来源：大连化学物理研究所
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