中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Vertically Aligned FeOOH/NiFe Layered Double Hydroxides Electrode for Highly Efficient Oxygen Evolution Reaction

文献类型:期刊论文

作者Yi, Baolian1; Chi, Jun1,2; Yu, Hongmei1; Qn, Bowen1,2; Fu, Li1,2; Jia, Jia1,2; Shao, Zhigang1
刊名ACS APPLIED MATERIALS & INTERFACES
出版日期2017-01-11
卷号9期号:1页码:464-471
关键词layered double hydroxides binder-free oxygen evolution reaction alkaline polymer electrolyte water electrolyzer water splitting
英文摘要Employing a low-cost and highly efficient electrocatalyst to replace Ir-based catalysts for oxygen evolution reaction (OER) has drawn increasing interest in renewable energy storage. In this work, a vertically aligned FeOOH/NiFe layered double hydroxides (LDHs) nanosheets supported on Ni foam (VA FeOOH/NiFe LDHs-NF) is prepared as a highly effective OER electrode in alkaline electrolyte. The VA FeOOH/NiFe LDHs-NF represents nanosheet arrays on nickel foam with some interspace among them. The vertically aligned and interlayer-structured architecture is binder-free and contributes to facile strain relaxation, relieving the exfoliation of the catalysts layer caused by the oxygen evolution process. The as-prepared electrode shows current densities of 10 and 500 mA cm(-2) at overpotentials of 208 and 288 mV, and good stability in a half-cell electrolyzer. Besides, the alkaline polymer electrolyte water electrolyzer (APE:WE) with this electrode showed 1.71 V at 200 mA cm(-2), and 2.041 V at 500 mA cm(-2), exhibiting the corresponding energy efficiency of 86.0% and 72. lower heating value of hydrogen), which is better than the typical commercial alkaline water electrolyzer.
WOS标题词Science & Technology ; Technology
类目[WOS]Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Science & Technology - Other Topics ; Materials Science
关键词[WOS]HIGH-PERFORMANCE SUPERCAPACITORS ; NICKEL COBALTITE NANOSTRUCTURES ; ALKALINE WATER ELECTROLYSIS ; HYDROGEN-PRODUCTION ; NI FOAM ; NANOSHEET ARRAYS ; BINDER-FREE ; OXIDATION ; FE ; ELECTROCATALYSTS
收录类别SCI
语种英语
WOS记录号WOS:000392037400056
源URL[http://cas-ir.dicp.ac.cn/handle/321008/151873]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Yi, Baolian,Chi, Jun,Yu, Hongmei,et al. Vertically Aligned FeOOH/NiFe Layered Double Hydroxides Electrode for Highly Efficient Oxygen Evolution Reaction[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(1):464-471.
APA Yi, Baolian.,Chi, Jun.,Yu, Hongmei.,Qn, Bowen.,Fu, Li.,...&Shao, Zhigang.(2017).Vertically Aligned FeOOH/NiFe Layered Double Hydroxides Electrode for Highly Efficient Oxygen Evolution Reaction.ACS APPLIED MATERIALS & INTERFACES,9(1),464-471.
MLA Yi, Baolian,et al."Vertically Aligned FeOOH/NiFe Layered Double Hydroxides Electrode for Highly Efficient Oxygen Evolution Reaction".ACS APPLIED MATERIALS & INTERFACES 9.1(2017):464-471.

入库方式: OAI收割

来源:大连化学物理研究所

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