Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography
文献类型：期刊论文
| 作者 | Lamprou, Alexandros2; Liu, Huwei1; Bai, Yu1; Svec, Frantisek2; Wang, Xin1,2 |
| 刊名 | JOURNAL OF SEPARATION SCIENCE
 |
| 出版日期 | 2016-12-01 |
| 卷号 | 39期号:23页码:4544-4548 |
| 关键词 | Chiral stationary phases Enantioselectivity Nano-liquid chromatography Metal-organic frameworks Polymer monoliths |
| 英文摘要 | A new approach to the preparation of enantioselective porous polymer monolithic columns with incorporated chiral metal-organic framework for nano-liquid chromatography has been developed. While no enantioseparation was achieved with monolithic poly(4-vinylpyridine-co-ethylene dimethacrylate) column, excellent separations of both enantiomers of (+/-)methyl phenyl sulfoxide were achieved with its counterpart prepared after admixing metalorganic framework [Zn-2(benzene dicarboxylate)(l-lactic acid)(dmf)], which is synthesized from zinc nitrate, L-lactic acid, and benzene dicarboxylic acid in the polymerization mixture. These novel monolithic columns combined selectivity of the chiral framework with the excellent hydrodynamic properties of polymer monoliths, may provide a great impact on future studies in the field of chiral analysis by liquid chromatography. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Analytical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | STATIONARY-PHASE ; MASS-SPECTROMETRY ; SMALL MOLECULES ; SEPARATION ; MICROEXTRACTION ; PERFORMANCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000393030100009 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151899]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Inst Analyt Chem,Coll Chem & Mol Engn, Beijing, Peoples R China 2.EO Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA |
| 推荐引用方式 GB/T 7714 | Lamprou, Alexandros,Liu, Huwei,Bai, Yu,et al. Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography[J]. JOURNAL OF SEPARATION SCIENCE,2016,39(23):4544-4548. |
| APA | Lamprou, Alexandros,Liu, Huwei,Bai, Yu,Svec, Frantisek,&Wang, Xin.(2016).Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography.JOURNAL OF SEPARATION SCIENCE,39(23),4544-4548. |
| MLA | Lamprou, Alexandros,et al."Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography".JOURNAL OF SEPARATION SCIENCE 39.23(2016):4544-4548. |
入库方式： OAI收割
来源：大连化学物理研究所
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