Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates
文献类型:期刊论文
作者 | Song, Xiangen1; Li, Cunyao1,3; Chen, Xingkun1,3; Lyu, Yuan1; Wang, Wenlong1; Wang, Tao1,3; Ding, Yunjie1,2; Zhang, Yan1,3 |
刊名 | RSC ADVANCES
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出版日期 | 2017 |
卷号 | 7期号:5页码:2836-2841 |
英文摘要 | A series of cross-linked polymer supported ionic liquids based on quaternary ammonium salts have been prepared using a facile method of radical polymerization. Styrene-functionalized quaternary ammonium chloride salts, which are derived from imidazole, trimethylamine, triethylamine and triethanolamine, were copolymerized with divinyl benzene (DVB) under solvothermal conditions. These polymer supported ionic liquids displayed high efficiency in catalytic conversion of CO2 to cyclic carbonates. Notably, to the best of our knowledge, it was the first time that the polymeric ionic liquid catalyst was applied in a continuous flow fixed-bed reactor. During the study period of 130 hours, the polymer supported ionic liquids exhibited high stability. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | MILD CONDITIONS ; CYCLOADDITION ; EPOXIDES ; FIXATION ; DIOXIDE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000393748600051 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151900] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Song, Xiangen,Li, Cunyao,Chen, Xingkun,et al. Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates[J]. RSC ADVANCES,2017,7(5):2836-2841. |
APA | Song, Xiangen.,Li, Cunyao.,Chen, Xingkun.,Lyu, Yuan.,Wang, Wenlong.,...&Zhang, Yan.(2017).Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates.RSC ADVANCES,7(5),2836-2841. |
MLA | Song, Xiangen,et al."Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates".RSC ADVANCES 7.5(2017):2836-2841. |
入库方式: OAI收割
来源:大连化学物理研究所
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