Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus
文献类型：期刊论文
| 作者 | Fan, Ronggang3; Yoneyama, Yoshiharu1; Yang, Guohui1; Tsubaki, Noritatsu1; Li, Jie1; Sun, Jian1,2 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2017-07-24 |
| 卷号 | 9期号:14页码:2668-2674 |
| 关键词 | Anderson-Schulz-Flory distribution biomass Fischer-Tropsch synthesis gasification jet fuel |
| 英文摘要 | Jet fuel is not easy to synthesize by the biomass-to-liquid (BTL) process owing to the limitation of the Anderson-Schulz-Flory (ASF) hydrocarbon distribution law in Fischer-Tropsch synthesis (FTS) with biomass-derived syngas (CO+H2). Here, we realized an anti-ASF distribution to selectively produce jet fuel from biomass on a large scale by addition of small amounts of 1-olefin, a FTS product, into syngas, enhancing jet fuel selectivity in hydrocarbons up to 64% and that in oil product to as high as 91%. The Co/SiO2 catalyst (300 g) was loaded into a flow-type three-phase reactor and 120h continuous operation was conducted by using the real-time on-line biomass- derived syngas from an entrained bed gasifier of biomass (240 kg day(-1)) of Mitsubishi Heavy Industries, Ltd. The production rate of liquid oil reached 720 g kg(cat)(-1)h(-1). The structure of the fresh and used catalyst was characterized in detail, accompanied with lab-scale data on reaction performance and catalyst properties. The stable technology process from biomass gasification to FTS, stable catalyst structure, and novel design of 1-olefin addition are the key to success in selectively converting biomass to jet fuel on a large scale. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | FISCHER-TROPSCH SYNTHESIS ; BIMODAL CATALYST ; COBALT ; CONVERSION ; NANOPARTICLES ; DEACTIVATION ; HYDROCARBONS ; PRODUCT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000406243100010 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151904]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Toyama, Dept Appl Chem, Sch Engn, Gofuku 3190, Toyama 9308555, Japan 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China 3.Shinka Co Ltd, Gofuku 3383-4, Toyama, Japan |
| 推荐引用方式 GB/T 7714 | Fan, Ronggang,Yoneyama, Yoshiharu,Yang, Guohui,et al. Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus[J]. CHEMCATCHEM,2017,9(14):2668-2674. |
| APA | Fan, Ronggang,Yoneyama, Yoshiharu,Yang, Guohui,Tsubaki, Noritatsu,Li, Jie,&Sun, Jian.(2017).Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus.CHEMCATCHEM,9(14),2668-2674. |
| MLA | Fan, Ronggang,et al."Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus".CHEMCATCHEM 9.14(2017):2668-2674. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。