Highly Flexible and Conductive Cellulose-Mediated PEDOT:PSS/MWCNT Composite Films for Supercapacitor Electrodes
文献类型：期刊论文
| 作者 | Li, Jian1; Zhao, Dawei1; Zhang, Qi1; Chen, Wenshuai1; Yi, Xin1; Liu, Shouxin1; Wang, Qingwen1; Liu, Yixing1; Yu, Haipeng1; Li, Xianfeng2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017-04-19 |
| 卷号 | 9期号:15页码:13213-13222 |
| 关键词 | cellulose carbon nanotubes conducting polymers electrodes flexibility supercapacitors |
| 英文摘要 | Recent improvements in flexible electronics have increased the need to develop flexible and lightweight power sources. However, current flexible electrodes are limited by low capacitance, poor mechanical properties, and lack of cycling stability, In this article, we describe an ionic liquid processed supramolecular assembly of, cellulose and 3,4-ethylenedioxythiophene for the formation of a flexible and conductive cellulose/poly(3,4-ethylenedioxythiophene) PEDOT:poly(styrene sulfonate) (PSS) composite matrix. On this base, multiwalled carbon nanotubes (MWCNTs) were incorporated into the matrix to fabricate an MWCNT-reinforced cellulose/PEDOT:PSS film (MCPP), which exhibited favorable flexibility and conductivity. The MCPP-based electrode displayed comprehensively excellent electrochemical properties, such as a low resistance of 0.45 Omega, a high specific capacitance of 485 F g(-1) at 1 A g(-l), and good cycling stability, with a capacity retention of 95% after 2000 cycles at 2 A g(-1). An MCPP-based symmetric solid-state supercapacitor with Ni foam as the current collector and PVA/KOH gel as the electrolyte exhibited a specific capacitance of 380 F g(-1) at 0.25 A g(-1) and achieved a maximum energy density of 13.2 Wh kg(-1) (0.25 A g(-l)) with a power density of 0.126 kW kg(-1) or an energy density of 4.86 Wh kg(-1) at 10 A g(-1), corresponding to a high power density of 4.99 kW kg(-1). Another kind of MCPP-based solid-state supercapacitor without the Ni foam showed excellent flexibility and a high volumetric capacitance of 50.4 F cm(-3) at 0.05 A cm(-3). Both the electrodes and the supercapacitors were environmentally stable and could be operated under remarkable deformation or high temperature without damage to their structural integrity or a significant decrease in capacitive performance. Overall, this work provides a strategy for the fabrication of flexible and conductive energy-storage films with ionic liquid-processed cellulose as a medium. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | ENERGY-STORAGE DEVICES ; HIGH-PERFORMANCE SUPERCAPACITORS ; ELECTRICAL-CONDUCTIVITY ; CARBON NANOTUBES ; PAPER ; GRAPHENE ; NANOCOMPOSITES ; POLYANILINE ; DISPERSIONS ; TEMPLATE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000399965700033 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151961]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Northeast Forestry Univ, Minist Educ, Key Lab Biobased Mat Sci & Technol, Harbin 150040, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jian,Zhao, Dawei,Zhang, Qi,et al. Highly Flexible and Conductive Cellulose-Mediated PEDOT:PSS/MWCNT Composite Films for Supercapacitor Electrodes[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(15):13213-13222. |
| APA | Li, Jian.,Zhao, Dawei.,Zhang, Qi.,Chen, Wenshuai.,Yi, Xin.,...&Li, Xianfeng.(2017).Highly Flexible and Conductive Cellulose-Mediated PEDOT:PSS/MWCNT Composite Films for Supercapacitor Electrodes.ACS APPLIED MATERIALS & INTERFACES,9(15),13213-13222. |
| MLA | Li, Jian,et al."Highly Flexible and Conductive Cellulose-Mediated PEDOT:PSS/MWCNT Composite Films for Supercapacitor Electrodes".ACS APPLIED MATERIALS & INTERFACES 9.15(2017):13213-13222. |
入库方式： OAI收割
来源：大连化学物理研究所
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