Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones
文献类型：期刊论文
| 作者 | Chang, Junbiao1; Liu, Bingxian1; Hu, Panjie1; Zhou, Xukai2; Bai, Dachang1; Li, Xingwei1,2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2017-04-21 |
| 卷号 | 19期号:8页码:2086-2089 |
| 英文摘要 | A Rh(III)-catalyzed addition of benzylic C(sp(3))-H bond to alpha,beta-unsaturated ketones/aldehydes has been realized, leading to efficient synthesis of gamma-aryl ketones/aldehydes. This atom-economic reaction proceeded under mild and redox-neutral conditions with a broad substrate scope. Besides benzylic C-H, allylic C-H bonds are also applicable when assisted by O-methyl ketoxime directing groups. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | C-H BOND ; CATALYZED CASCADE CYCLIZATION ; ROOM-TEMPERATURE ; INTERMOLECULAR AMIDATION ; CONVERGENT SYNTHESIS ; RHODIUM(III)-CATALYZED AMIDATION ; NUCLEOPHILIC-ADDITION ; CONJUGATE ADDITION ; CARBONYL-COMPOUNDS ; DIRECTING GROUPS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400123600038 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151966]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Henan Normal Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chang, Junbiao,Liu, Bingxian,Hu, Panjie,et al. Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones[J]. ORGANIC LETTERS,2017,19(8):2086-2089. |
| APA | Chang, Junbiao,Liu, Bingxian,Hu, Panjie,Zhou, Xukai,Bai, Dachang,&Li, Xingwei.(2017).Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones.ORGANIC LETTERS,19(8),2086-2089. |
| MLA | Chang, Junbiao,et al."Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones".ORGANIC LETTERS 19.8(2017):2086-2089. |
入库方式： OAI收割
来源：大连化学物理研究所
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