A hollow Mo/HZSM-5 zeolite capsule catalyst: preparation and enhanced catalytic properties in methane dehydroaromatization
文献类型：期刊论文
| 作者 | Yoneyama, Yoshiharu2; Zhu, Pengfei1,2; Yang, Guohui2; Sun, Jian3; Fan, Ronggang4; Zhang, Peipei2; Tsubaki, Noritatsu2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2017-05-14 |
| 卷号 | 5期号:18页码:8599-8607 |
| 英文摘要 | A hollow Silicalite-1-HZSM-5 zeolite capsule structure (H-S-Z) embedded with Mo nanoparticles was designed and prepared. The H-S-Z was obtained by a dual-layer hydrothermal synthesis method using activated carbon (AC) as a hard template via self-assembly combined hydrothermal crystallization. One layer of Silicalite-1 zeolite shell was first synthesized on the AC core under neutral-like synthesis conditions. Then, a HZSM-5 zeolite shell was synthesized on this Silicalite-1 zeolite shell enveloping the AC core, followed by calcination in air to remove the core AC. After being loaded with Mo, this hollow zeolite capsule catalyst was tested in a methane dehydroaromatization (MDA) reaction. Compared with the conventional solid catalyst, the Mo/H-S-Z catalyst significantly improved the methane conversion, formation rate of the benzene product, and catalytic stability, and inhibited the carbon deposition, due to the accelerated mass-transfer rate in the hollow structure. Furthermore, the catalyst deactivation derived from the side reactions such as poly-aromatics or coke formation at the inner zeolite could be eliminated. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
| 关键词[WOS] | AROMATIZATION ; SELECTIVITY ; DEHYDROGENATION ; ISOPARAFFINS ; MOLYBDENUM ; CRYSTALS ; ABSENCE ; SYNGAS ; OXYGEN |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400983400047 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151968]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Peoples R China 2.Toyama Univ, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China 4.Shinka Co Ltd, Gofuku 3383-4, Toyama 9308555, Japan |
| 推荐引用方式 GB/T 7714 | Yoneyama, Yoshiharu,Zhu, Pengfei,Yang, Guohui,et al. A hollow Mo/HZSM-5 zeolite capsule catalyst: preparation and enhanced catalytic properties in methane dehydroaromatization[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(18):8599-8607. |
| APA | Yoneyama, Yoshiharu.,Zhu, Pengfei.,Yang, Guohui.,Sun, Jian.,Fan, Ronggang.,...&Tsubaki, Noritatsu.(2017).A hollow Mo/HZSM-5 zeolite capsule catalyst: preparation and enhanced catalytic properties in methane dehydroaromatization.JOURNAL OF MATERIALS CHEMISTRY A,5(18),8599-8607. |
| MLA | Yoneyama, Yoshiharu,et al."A hollow Mo/HZSM-5 zeolite capsule catalyst: preparation and enhanced catalytic properties in methane dehydroaromatization".JOURNAL OF MATERIALS CHEMISTRY A 5.18(2017):8599-8607. |
入库方式： OAI收割
来源：大连化学物理研究所
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