Atomic-scale topochemical preparation of crystalline Fe3+-doped beta-Ni(OH)(2) for an ultrahighrate oxygen evolution reaction
文献类型：期刊论文
| 作者 | Zhu, Xuefeng1; Zhu, Kaiyue1,2; Liu, Huanying1; Li, Mingrun1; Li, Xuning2,3,4; Wang, Junhu2,3,4; Yang, Weishen1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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| 出版日期 | 2017-05-07 |
| 卷号 | 5期号:17页码:7753-7758 |
| 英文摘要 | The development of highly efficient and affordable electrocatalysts for the sluggish oxygen evolution reaction (OER) has been considered as a great challenge to the practical applications for water splitting and in rechargeable metal-air batteries. Herein, we report active and robust OER catalysts of Fe3+-doped beta-Ni(OH)(2) prepared via an atomic-scale topochemical transformation route. Based on the premise that all Fe3+ is incorporated into the beta-Ni(OH)(2) lattice, the OER activity increases directly with the content of Fe3+. The Fe(0.5)-doped beta-Ni(OH)(2) catalyst affords a current density of 10 mA cm(-2) at an overpotential as low as 0.26 V and a small Tafel slope of 32 mv dec(-1). Comparing the state-of-the-art IrO2 catalyst, the Fe(0.5)-doped beta-Ni(OH)(2) catalyst exhibits higher activity and stability from galvanostatic tests at 10 mA cm(-2). Additionally, we experimentally demonstrate that Fe(0.5)-doped beta-Ni(OH)(2) exerts higher OER activity than Fe(0.5)-doped alpha-Ni(OH)(2). All evidence indicates that Fe and the beta-Ni(OH)(2) matrix play an important role in NiFe-based catalysts. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
| 关键词[WOS] | LAYERED DOUBLE HYDROXIDE ; WATER OXIDATION ; MOSSBAUER-SPECTROSCOPY ; PHASE-TRANSFORMATION ; NICKEL HYDROXIDES ; AIR BATTERIES ; NIFE ; ELECTROCATALYSTS ; FILM ; EFFICIENT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400553700009 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151983]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Catalysts & New Mat Aerosp, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Xuefeng,Zhu, Kaiyue,Liu, Huanying,et al. Atomic-scale topochemical preparation of crystalline Fe3+-doped beta-Ni(OH)(2) for an ultrahighrate oxygen evolution reaction[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(17):7753-7758. |
| APA | Zhu, Xuefeng.,Zhu, Kaiyue.,Liu, Huanying.,Li, Mingrun.,Li, Xuning.,...&Yang, Weishen.(2017).Atomic-scale topochemical preparation of crystalline Fe3+-doped beta-Ni(OH)(2) for an ultrahighrate oxygen evolution reaction.JOURNAL OF MATERIALS CHEMISTRY A,5(17),7753-7758. |
| MLA | Zhu, Xuefeng,et al."Atomic-scale topochemical preparation of crystalline Fe3+-doped beta-Ni(OH)(2) for an ultrahighrate oxygen evolution reaction".JOURNAL OF MATERIALS CHEMISTRY A 5.17(2017):7753-7758. |
入库方式： OAI收割
来源：大连化学物理研究所
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