Environmentally benign and economic synthesis of covalent triazine-based frameworks
文献类型：期刊论文
| 作者 | Deng, Wei-Qiao2; Zhang, Ling1,2; Liu, Xue2; Yang, Rui-Xia2; Huang, Nian-Yu1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 38期号:3页码:583-588 |
| 关键词 | Covalent triazine-based framework Aryl bromide Cyanation Potassium hexacyanoferrate(II) Palladium acetate |
| 英文摘要 | Covalent triazine-based frameworks (CTFs) are important microporous materials with a wide range of applications. Here, we demonstrate an environmentally benign and economic synthetic pathway to CTFs. The monomers used for CTFs, aromatic nitriles, were obtained by cyanation using nontoxic potassium hexacyanoferrate(II) in place of commonly used toxic cyanides. Then, the CTFs were synthesized by trimerization of the corresponding cyano monomers in molten zinc chloride. A series of CTFs was synthesized, and the highest Brunauer-Emmett-Teller surface area measured in this series was 2404 m(2)/g. Among the synthesized CTFs, CTFDCP exhibited excellent CO2 adsorption properties, with a CO2 uptake of 225 mg/g at 0 degrees C. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | PALLADIUM-CATALYZED CYANATION ; METAL-FREE ELECTROCATALYSTS ; OXYGEN REDUCTION REACTION ; ORGANIC FRAMEWORKS ; ARYL CHLORIDES ; CO2 ; POLYMER ; CARBON ; CAPTURE ; STORAGE |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000400125100020 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151992]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.China Three Gorges Univ, Coll Biol & Pharmaceut Sci, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Hunan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Wei-Qiao,Zhang, Ling,Liu, Xue,et al. Environmentally benign and economic synthesis of covalent triazine-based frameworks[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(3):583-588. |
| APA | Deng, Wei-Qiao,Zhang, Ling,Liu, Xue,Yang, Rui-Xia,&Huang, Nian-Yu.(2017).Environmentally benign and economic synthesis of covalent triazine-based frameworks.CHINESE JOURNAL OF CATALYSIS,38(3),583-588. |
| MLA | Deng, Wei-Qiao,et al."Environmentally benign and economic synthesis of covalent triazine-based frameworks".CHINESE JOURNAL OF CATALYSIS 38.3(2017):583-588. |
入库方式： OAI收割
来源：大连化学物理研究所
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