Ethylene glycol production from glucose over W-Ru catalysts: Maximizing yield by kinetic modeling and simulation
文献类型：期刊论文
| 作者 | Wang, Xiaodong; Zhao, Guanhong; Zheng, Mingyuan; Sun, Ruiyan; Tai, Zhijun; Pang, Jifeng; Wang, Aiqin; Zhang, Tao |
| 刊名 | AICHE JOURNAL
 |
| 出版日期 | 2017-06-01 |
| 卷号 | 63期号:6页码:2072-2080 |
| 关键词 | biomass glucose ethylene glycol reaction kinetics modeling |
| 英文摘要 | The kinetics of glucose conversion to ethylene glycol (EG) in the presence of ammonium paratungstate and Ru/AC catalysts was studied to model and predict the reaction performance under a range of conditions. A mathematical model was established through the rational simplification of the reaction network on the basis of a continuous stirred-tank model. The kinetic data of six major reactions in the network were experimentally measured, and the analytical expressions of overall reaction kinetics were obtained by introducing the kinetic data to the model. Yields of EG, hexitols and gas were described as functions of the reaction temperature, the concentration of glucose in the feedstock and the feeding rate. The simulation results matched the experimental data of glucose conversion, demonstrating the validity of the model and method for studying the overall kinetics of glucose conversion to EG over W-Ru catalysts. (c) 2016 American Institute of Chemical Engineers AIChE J, 63: 2072-2080, 2017 |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | 1,2-PROPYLENE GLYCOL ; RUTHENIUM CATALYST ; TUNGSTEN CARBIDE ; REACTION NETWORK ; RANEY NI ; CONVERSION ; CELLULOSE ; BIOMASS ; 1,2-PROPANEDIOL ; HYDROGENOLYSIS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400658400023 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151997]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiaodong,Zhao, Guanhong,Zheng, Mingyuan,et al. Ethylene glycol production from glucose over W-Ru catalysts: Maximizing yield by kinetic modeling and simulation[J]. AICHE JOURNAL,2017,63(6):2072-2080. |
| APA | Wang, Xiaodong.,Zhao, Guanhong.,Zheng, Mingyuan.,Sun, Ruiyan.,Tai, Zhijun.,...&Zhang, Tao.(2017).Ethylene glycol production from glucose over W-Ru catalysts: Maximizing yield by kinetic modeling and simulation.AICHE JOURNAL,63(6),2072-2080. |
| MLA | Wang, Xiaodong,et al."Ethylene glycol production from glucose over W-Ru catalysts: Maximizing yield by kinetic modeling and simulation".AICHE JOURNAL 63.6(2017):2072-2080. |
入库方式： OAI收割
来源：大连化学物理研究所
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