Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols
文献类型：期刊论文
| 作者 | Mishra, Manish2,3; Tayade, Kamlesh N.1; Wang, Lianyue1; Shang, Sensen1; Dai, Wen1; Gao, Shuang1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2017-04-01 |
| 卷号 | 38期号:4页码:758-766 |
| 关键词 | Epoxide ring opening Acid catalysis Metal triflate Grafted catalyst Mesoporous silica |
| 英文摘要 | Metal (Al, Ti, Zr) triflate grafted mesoporous SBA-15 (AlTf/S, TiTf/S, ZrTf/S) samples were synthesized as inexpensive solid acid materials by a simple one-pot-two-step synthesis methodology. These materials were characterized by X-ray diffraction, N-2-sorption, thermogravimetric analysis, Fourier transform infrared spectroscopy (FT-IR), in-situ pyridine FT-IR spectroscopy, and elemental analysis. ZrTf/S was found to be a highly efficient and reusable solid acid catalyst for ring opening of epoxides with amines and alcohols and produced beta-amino alcohols and beta-alkoxy alcohols respectively under ambient reaction conditions. The ZrTf/S catalyst showed the highest activity, which was attributed to its high acidity compared with that of the Ti and Al containing samples. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | FRIEDEL-CRAFTS ACYLATION ; ASYMMETRIC AMINOHYDROXYLATION ; CATIONIC-POLYMERIZATION ; MESOPOROUS SILICA ; ORGANIC-SYNTHESIS ; SCANDIUM ; MCM-41 ; ALUMINOSILICATES ; AMINOLYSIS ; ALUMINUM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400419900016 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152001]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Dharmsinh Desai Univ, Fac Technol, Dept Chem Engn, Nadiad 387001, Gujarat, India 3.Dharmsinh Desai Univ, Fac Technol, Shah Schulman Ctr Surface Sci & Nanotechnol, Nadiad 387001, Gujarat, India |
| 推荐引用方式 GB/T 7714 | Mishra, Manish,Tayade, Kamlesh N.,Wang, Lianyue,et al. Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(4):758-766. |
| APA | Mishra, Manish,Tayade, Kamlesh N.,Wang, Lianyue,Shang, Sensen,Dai, Wen,&Gao, Shuang.(2017).Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols.CHINESE JOURNAL OF CATALYSIS,38(4),758-766. |
| MLA | Mishra, Manish,et al."Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols".CHINESE JOURNAL OF CATALYSIS 38.4(2017):758-766. |
入库方式： OAI收割
来源：大连化学物理研究所
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