A Bunch-Like Tertiary Amine Grafted Polysulfone Membrane for VRFBs with Simultaneously High Proton Conductivity and Low Vanadium Ion Permeability
文献类型：期刊论文
| 作者 | Wu, Chunxiao1; Tan, Qinglong1; Lu, Shanfu1; Si, Jiangju1; Wang, Haining1; Li, Xianfeng2; Xiang, Yan1 |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2017-04-01 |
| 卷号 | 38期号:8 |
| 关键词 | proton conductivity tertiary amine vanadium ion permeability vanadium redox flow batteries |
| 英文摘要 | Novel polysulfone membranes with bunch-like tertiary amine groups are synthesized with high ion selectivity and outstanding chemical stability for vanadium redox flow batteries (VRFBs). The bunch-like tertiary amine groups simultaneously act as an ionic conductor for proton hopping and vanadium ion transport obstacles. The performance of the membrane is tuned via controlling the grafting degree of the chloromethylated polysulfone. The results show that membranes show increasing proton over vanadium ion (sigma/p) selectivity with increasing functional tertiary groups. VRFBs assembled with the prepared membranes demonstrate an impressive Coulombic efficiency of 98.9% and energy efficiency of 90.9% at a current density of 50 mA cm(-2). Furthermore, the prepared membrane reported in this work shows excellent stability in 1 m VO2+ solution at 35 degrees C over 240 h. Overall, the synthesized polymers provide a new insight into the design of high-performance membranes toward VRFB applications. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | REDOX FLOW BATTERIES ; ANION-EXCHANGE MEMBRANES ; POROUS MEMBRANES ; FUEL-CELLS ; SELECTIVITY ; DEGRADATION ; ELECTROLYTE ; STABILITY ; MECHANISM ; DESIGN |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400377600003 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152005]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Beihang Univ, Sch Space & Environm, Beijing Key Lab Bioinspired Energy Mat & Devices, Beijing 100191, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Chunxiao,Tan, Qinglong,Lu, Shanfu,et al. A Bunch-Like Tertiary Amine Grafted Polysulfone Membrane for VRFBs with Simultaneously High Proton Conductivity and Low Vanadium Ion Permeability[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2017,38(8). |
| APA | Wu, Chunxiao.,Tan, Qinglong.,Lu, Shanfu.,Si, Jiangju.,Wang, Haining.,...&Xiang, Yan.(2017).A Bunch-Like Tertiary Amine Grafted Polysulfone Membrane for VRFBs with Simultaneously High Proton Conductivity and Low Vanadium Ion Permeability.MACROMOLECULAR RAPID COMMUNICATIONS,38(8). |
| MLA | Wu, Chunxiao,et al."A Bunch-Like Tertiary Amine Grafted Polysulfone Membrane for VRFBs with Simultaneously High Proton Conductivity and Low Vanadium Ion Permeability".MACROMOLECULAR RAPID COMMUNICATIONS 38.8(2017). |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。