Nitrogen-doped porous carbon derived from Fe-MIL nanocrystals as an electrocatalyst for efficient oxygen reduction
文献类型：期刊论文
| 作者 | Geng, Jiangtao2; Zhang, Hongjie1,2; Bai, Yangzhi1,2; Yi, Baolian2; Shao, Zhigang2; Yang, Limeng1,2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:36页码:22610-22618 |
| 英文摘要 | Exploring cheap and stable electrocatalysts to replace Pt for the oxygen reduction reaction (ORR) is now the key issue for the large-scale application of fuel cells. Herein, we report a novel mesoporous carbon material prepared by one-step pyrolysis of a dicyandiamide (DCD)-doped iron-based metal organic framework (MOF) compound-Materiaux de l'Institute Lavosier-101(Fe) (MIL-101(Fe)). The as-prepared nitrogen mesoporous carbon (MIL-5 DCD-800) is characterized by transmission electron microscopy (TEM), Xray powder diffraction (XRD), N-2 sorption isotherms and X-ray photoelectron spectroscopy. MIL-5 DCD-800 shows an onset potential of 1.08 V (vs. RHE) and a half-wave potential of 0.86 V (vs. RHE) in 0.1 M KOH, which are similar to those of commercial Pt/C (1.05 V@ 0.05 mA cm(-2)). Furthermore, the electrocatalyst also possesses a much better stability and resistance to methanol crossover than Pt/C. This excellent performance is attributable to the presence of pyridinic- and graphitic-N together with abundant Fe active sites that promotes the four-electron process in the ORR. High pore volume and appropriate mesopores boost the mass transfer and reactivity during electrocatalysis. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | NONPRECIOUS METAL ELECTROCATALYSTS ; ENCAPSULATED IRON NANOPARTICLES ; ELECTROLYTE FUEL-CELLS ; HIGHLY EFFICIENT ; RECENT PROGRESS ; CATALYSTS ; GRAPHENE ; COMPOSITE ; FRAMEWORKS ; MECHANISM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400157700075 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152006]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 2.Chinese Acad Sci, DICP, Dalian Natl Labs Clean Energy DNL, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Geng, Jiangtao,Zhang, Hongjie,Bai, Yangzhi,et al. Nitrogen-doped porous carbon derived from Fe-MIL nanocrystals as an electrocatalyst for efficient oxygen reduction[J]. RSC ADVANCES,2017,7(36):22610-22618. |
| APA | Geng, Jiangtao,Zhang, Hongjie,Bai, Yangzhi,Yi, Baolian,Shao, Zhigang,&Yang, Limeng.(2017).Nitrogen-doped porous carbon derived from Fe-MIL nanocrystals as an electrocatalyst for efficient oxygen reduction.RSC ADVANCES,7(36),22610-22618. |
| MLA | Geng, Jiangtao,et al."Nitrogen-doped porous carbon derived from Fe-MIL nanocrystals as an electrocatalyst for efficient oxygen reduction".RSC ADVANCES 7.36(2017):22610-22618. |
入库方式： OAI收割
来源：大连化学物理研究所
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