中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
REEVALUATION OF 2,2-BIPYRIDINE AND PYRAZINE AS PROMOTERS FOR DIRECT ELECTRON-TRANSFER BETWEEN CYTOCHROME-C AND METAL-ELECTRODES

文献类型:期刊论文

作者ZHOU CL ; YE SY ; KIM JH ; COTTON TM ; YU XJ ; LU TH ; DONG SJ
刊名journal of electroanalytical chemistry
出版日期1991
卷号319期号:1-2页码:71-83
关键词ENHANCED RAMAN-SCATTERING MODIFIED GOLD ELECTRODES DIRECT ELECTROCHEMISTRY COMPETITIVE ADSORPTION VOLTAMMETRIC RESPONSE GRAPHITE-ELECTRODES SILVER ELECTRODE REDUCTION PROTEINS 2,2'-BIPYRIDINE
ISSN号0022-0728
中文摘要results from previous electrochemical studies have indicated that 2,2'-bipyridine and pyrazine do not function as promoters for heterogeneous electron transfer between cytochrome c and metal electrodes. their lack of activity was attributed to the improper positioning of the two functional groups in 2,2'-bipyridine and the inefficient length of pyrazine. in the present study it was determined that both 2,2'-bipyridine and pyrazine act as promoters when self-absorbed over a sufficiently long dipping time or at roughened electrodes. the promoter characteristics of these two molecules were studied and compared with those of 4,4'-bipyridine. the difference in their promoter behavior appears to result primarily from their different strengths of adsorption and not because electrodes modified with 2,2'-bipyridine or pyrazine are unsuitable for accelerating direct electron transfer reactions in cytochrome c. these results have implications regarding the mechanism(s) of promoter effects in electrochemical reactions of cytochrome c.
收录类别SCI收录期刊论文
语种英语
公开日期2011-03-03 ; 2011-06-10
源URL[http://ir.ciac.jl.cn/handle/322003/38295]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
ZHOU CL,YE SY,KIM JH,et al. REEVALUATION OF 2,2-BIPYRIDINE AND PYRAZINE AS PROMOTERS FOR DIRECT ELECTRON-TRANSFER BETWEEN CYTOCHROME-C AND METAL-ELECTRODES[J]. journal of electroanalytical chemistry,1991,319(1-2):71-83.
APA ZHOU CL.,YE SY.,KIM JH.,COTTON TM.,YU XJ.,...&DONG SJ.(1991).REEVALUATION OF 2,2-BIPYRIDINE AND PYRAZINE AS PROMOTERS FOR DIRECT ELECTRON-TRANSFER BETWEEN CYTOCHROME-C AND METAL-ELECTRODES.journal of electroanalytical chemistry,319(1-2),71-83.
MLA ZHOU CL,et al."REEVALUATION OF 2,2-BIPYRIDINE AND PYRAZINE AS PROMOTERS FOR DIRECT ELECTRON-TRANSFER BETWEEN CYTOCHROME-C AND METAL-ELECTRODES".journal of electroanalytical chemistry 319.1-2(1991):71-83.

入库方式: OAI收割

来源:长春应用化学研究所

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