SYNTHESIS AND MOLECULAR-STRUCTURE OF THE 5-COORDINATE ZIRCONIUM COMPLEX (CH3C5H4)2ZRCL(ALPHA-C10H7COO)
文献类型：期刊论文
| 作者 | WANG ZQ ; LU SW ; GUO HF ; HU NH ; LIU YS |
| 刊名 | polyhedron
 |
| 出版日期 | 1991 |
| 卷号 | 10期号:19页码:2341-2345 |
| 关键词 | ORGANOMETALLIC COMPOUNDS BENT METALLOCENES CRYSTAL-STRUCTURE DERIVATIVES |
| ISSN号 | 0277-5387 |
| 通讯作者 | wang zq |
| 中文摘要 | bis(methylcyclopentadienyl)chloro(alpha-naphthoyloxy)zirconium, (ch3c5h4)2zr cl(alpha-c10h7coo), has been synthesized by the reaction between (mecp)2zrcl2 and equimolar sodium alpha-naphthoate in toluene at room temperature. the molecular structure of the title complex was determined by x-ray diffraction. the molecules have a five-coordinate bent metallocene structure in which the alpha-naphthoxyligand is bidentate [zr-o, 2.317(2), 2.260(2) angstrom]. the remaining distances are [zr-cl, 2.521(1) angstrom; zr-c, 480-2, 565 angstrom; zr-cent-ch3c5h4 2.217 and 2.230 angstrom]. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-03-03 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/38339]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | WANG ZQ,LU SW,GUO HF,et al. SYNTHESIS AND MOLECULAR-STRUCTURE OF THE 5-COORDINATE ZIRCONIUM COMPLEX (CH3C5H4)2ZRCL(ALPHA-C10H7COO)[J]. polyhedron,1991,10(19):2341-2345. |
| APA | WANG ZQ,LU SW,GUO HF,HU NH,&LIU YS.(1991).SYNTHESIS AND MOLECULAR-STRUCTURE OF THE 5-COORDINATE ZIRCONIUM COMPLEX (CH3C5H4)2ZRCL(ALPHA-C10H7COO).polyhedron,10(19),2341-2345. |
| MLA | WANG ZQ,et al."SYNTHESIS AND MOLECULAR-STRUCTURE OF THE 5-COORDINATE ZIRCONIUM COMPLEX (CH3C5H4)2ZRCL(ALPHA-C10H7COO)".polyhedron 10.19(1991):2341-2345. |
入库方式： OAI收割
来源：长春应用化学研究所
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