DETERMINATION OF THE MARK-HOUWINK EQUATION FOR CHITOSANS WITH DIFFERENT DEGREES OF DEACETYLATION
文献类型:期刊论文
作者 | WEI W ; BO SQ ; LI SQ ; WEN Q |
刊名 | international journal of biological macromolecules |
出版日期 | 1991 |
卷号 | 13期号:5页码:281-285 |
ISSN号 | 0141-8130 |
通讯作者 | wei w |
中文摘要 | the values of k and alpha in the mark-houwink equation have been determined for chitosans with different degrees of deacetylation (dd) (69, 84, 91 and 100% respectively), in 0.2 m ch3cooh/0.1 m ch3coona aqueous solution at 30-degrees-c by the light scattering method. it was shown that the values of alpha-decreased from 1.12 to 0.81 and the values of k increased from 0.104 x 10(-3) to 16.80 x 10(-3) ml/g, when the dd varied from 69 to 100%. this is due to a reduction of rigidity of the molecular chain and an increase of the electrostatic repulsion force of the ionic groups along the polyelectrolyte chain in chitosan solution, when the dd of chitosan increases gradually. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2011-03-03 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/38351] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | WEI W,BO SQ,LI SQ,et al. DETERMINATION OF THE MARK-HOUWINK EQUATION FOR CHITOSANS WITH DIFFERENT DEGREES OF DEACETYLATION[J]. international journal of biological macromolecules,1991,13(5):281-285. |
APA | WEI W,BO SQ,LI SQ,&WEN Q.(1991).DETERMINATION OF THE MARK-HOUWINK EQUATION FOR CHITOSANS WITH DIFFERENT DEGREES OF DEACETYLATION.international journal of biological macromolecules,13(5),281-285. |
MLA | WEI W,et al."DETERMINATION OF THE MARK-HOUWINK EQUATION FOR CHITOSANS WITH DIFFERENT DEGREES OF DEACETYLATION".international journal of biological macromolecules 13.5(1991):281-285. |
入库方式: OAI收割
来源:长春应用化学研究所
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